N,N-Dimethylbenzamide synthesis
- Product Name:N,N-Dimethylbenzamide
- CAS Number:611-74-5
- Molecular formula:C9H11NO
- Molecular Weight:149.19
124-40-3
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$18.00/100ml
65-85-0
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$10.00/25 g
611-74-5
213 suppliers
$10.00/5g
Yield:611-74-5 75%
Reaction Conditions:
with tetrabutylammomium bromide;iodine;potassium hydroxide in water at 20; for 2.5 h;Irradiation;
Steps:
General procedure for the catalytic reactions
General procedure: A 10 mL quartz tube equipped was charged with aniline (0.70 mmol), benzoic acid (0.50 mmol), TBAB (0.5 mmol), KOH (1.0 mmol), I2 (0.10 mmol), and water (2.5 mL). The reaction mixture was stirred under irradiation of sunlight at room temperature for 2.5 h. After the reaction was completed, the organic layer was collected by ethyl acetate extraction. The solution of the crude product was concentrated in vacuo, and the residue was purified by column chromatography on a silica gel (petroleum ether/ethyl acetate=5/1) to afford the target product as a white solid.
References:
Wang, Jin;Hou, Huiqing;Hu, Yongzhi;Lin, Jin;Wu, Min;Zheng, Zhiqiang;Xu, Xiuzhi [Tetrahedron Letters,2021,vol. 65,art. no. 152801] Location in patent:supporting information
124-40-3
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$18.00/100ml
100-51-6
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$5.00/100g
611-74-5
213 suppliers
$10.00/5g
100-52-7
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$17.30/2g
124-40-3
530 suppliers
$18.00/100ml
611-74-5
213 suppliers
$10.00/5g
137-26-8
304 suppliers
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65-85-0
1383 suppliers
$10.00/25 g
611-74-5
213 suppliers
$10.00/5g
93-97-0
384 suppliers
$6.00/25g
124-40-3
530 suppliers
$18.00/100ml
611-74-5
213 suppliers
$10.00/5g