Triphenylen Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R41:Gefahr ernster Augensch?den.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S39:Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
white to beige crystalline needles
Verwenden
Triphenylene is a polycyclic aromatic hydrocarbon (PAH) that can be isolated from coal tar. Triphenylene emits fluorescence in the ultraviolet region and is a useful compound for developing semiconductor devices.
Definition
ChEBI: Triphenylene is an ortho-fused polycyclic arene consisting of four fused benzene rings.
synthetische
Triphenylene synthesis: 2-Chlorobenzoic acid(78mg, 0.5mmol), iodonium salt (236mg, 0.55mmol), palladium acetate (2.8mg, 0.0125mmol), potassium carbonate (152mg, 1.1mmol) were dissolved in 3mL of NMP solvent was heated to 110 °C and stirred for 17 hours, cooled to room temperature, extracted with ethyl acetate, washed with saturated sodium chloride solution, dried over anhydrous sodium sulfate, filtered, concentrated, and subjected to column chromatography to obtain 92 mg of triphenylene as a white solid, The yield was 80%.
Allgemeine Beschreibung
Triphenylene belongs to the class of polycyclic aromatic hydrocarbons, which is commonly employed as a substrate for use as a precursor for the synthesis of graphenes, carbon nanotubes, buckminsterfullerenes as well as polycyclic heteroaromatics.
l?uterung methode
Purify triphenylene by zone refining or crystallisation from EtOH or CHCl3 and sublime. [Beilstein 5 IV 2556.]
Triphenylen Upstream-Materialien And Downstream Produkte
Upstream-Materialien
2,2'-Dibromobiphenyl
1H-3-Benzazepine, 2,3,4,5-tetrahydro-3-methyl-
2-Iodbiphenyl
1,2,3,4,5,6,7,8,9,10,11,12-Dodecahydrotriphenylen
BIPHENYLENE
2-Chlorbiphenyl
diphenyleneiodonium trifluoromethanesulfonate
1-Brom-2-fluorbenzol
2-Bromobiphenyl
1,2-Dibrombenzol
2-Brombenzoesure
1,2-bis(4,4,5,5-tetramethyl-[1,3,2]dioxabororan-2-yl)benzene
5,5-diMethyl-5H-dibenzo[b,d]stannole
o-Terphenyl
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
Downstream Produkte
