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ChemicalBook CAS DataBase List ETHYL 1-(2-CHLOROACETYL)-4-PIPERIDINECARBOXYLATE
318280-71-6

ETHYL 1-(2-CHLOROACETYL)-4-PIPERIDINECARBOXYLATE synthesis

1synthesis methods
-

Yield:318280-71-6 100%

Reaction Conditions:

in dichloromethane at 0; for 1 h;

Steps:

General Procedure 7 (GP7) - N-acetylation of secondary amine with 2-chloroacetyl chloride:

General procedure: Secondary amine (1.0eq.) was dissolved in DCM (100mL), cooled on an ice-bath, and then 2-chloroacetyl chloride (0.5eq.) was added. The reaction mixture was stirred on ice-bath for 1h, washed with H2O (2×70mL), saturated brine (70mL), dried over Na2SO4, filtered, and the volatiles were evaporatedin vacuo.

References:

Knez, Damijan;Hrast, Martina;Frlan, Rok;Pi?lar, Anja;?akelj, Simon;Kos, Janko;Gobec, Stanislav [Bioorganic Chemistry,2022,vol. 119,art. no. 105581]

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