Azidoacetic acid methyl ester

$15 - $6000
Product name: Azidoacetic acid methyl ester
CAS: 1816-92-8
MF: C3H5N3O2
MW: 115.0907
EINECS:
MDL Number:MFCD01311034
Synonyms:Azidoacetic acid methyl ester;2-Azido-acetic acid Methyl ester;Acetic acid, 2-azido-, Methyl ester;Methyl 2-azidoacetate 97%;Methyl 2-azidoacetate - M3461;methyl 3-diazo-3-azaprop-3-enoate

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Brand

Package

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Acrotein	AS00199	Methyl 2-azidoacetate 97%	25g	$440	2021-12-16	Buy
AK Scientific	X5179	Methyl 2-azidoacetate	5g	$117	2021-12-16	Buy
Oakwood	047876	Methyl azidoacetate	1g	$15	2021-12-16	Buy
Oakwood	047876	Methyl azidoacetate	5g	$50	2021-12-16	Buy
Oakwood	047876	Methyl azidoacetate	25g	$190	2021-12-16	Buy
Sigma-Aldrich	738859	Methyl 2-azidoacetate 97%	5g	$157	2023-06-20	Buy
SynChem	SC-29904	Methylazidoacetate 95%	5kg	$6000	2021-12-16	Buy
SynChem	SC-29904	Methylazidoacetate 95%	1kg	$2500	2021-12-16	Buy
SynChem	SC-29904	Methylazidoacetate 95%	100g	$800	2021-12-16	Buy
Synthonix	M3461	Methyl 2-azidoacetate 97%	1g	$15	2021-12-16	Buy
Synthonix	M3461	Methyl 2-azidoacetate 97%	5g	$45	2021-12-16	Buy
Synthonix	M3461	Methyl 2-azidoacetate 97%	25g	$160	2021-12-16	Buy
Synthonix	M3461	Methyl 2-azidoacetate 97%	50g	$230	2021-12-16	Buy
TRC	M331468	Methyl 2-azidoacetate	50mg	$60	2021-12-16	Buy

Properties

Boiling point :35 °C
Density :1.182 g/mL at 25 °C
refractive index :n20/D1.440
Flash point :48℃
form :liquid

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H226	Flammable liquid and vapour	Flammable liquids	Category 3	Warning
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Methyl 2-azidoacetate is widely used as a precursor to build triazole derivatives via alkyne-azide click chemistry. Some of the examples include the synthesis of coumarin-triazole derivatives as potential antiplasmodial agents and macrocyclic triazole containing largazole analogs as histone deacetylases-1 (HDAC1) inhibitors.
It can be used to synthesize various pyrrole derivatives by Knoevenagel condensation as in the synthesis of near-infrared boron dipyrromethene (BODIPY) donors for organic tandem solar cells.
It can also be used in Hemetsberger-Knittel synthesis of substituted 5-, 6-, and 7-azaindoles.
Synthesis of highly fluorescent pyreno[2,1-b]pyrroles using methyl 2-azidoacetate as one of the reagents.

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