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      Chemical Safety Data Sheet MSDS / SDS

      Dichloromaleic anhydride

      Revision Date:2024-12-21Revision Number:1

      SECTION 1: Identification of the substance/mixture and of the company/undertaking

      Product identifier

      • Product name: Dichloromaleic anhydride
      • CBnumber: CB5185881
      • CAS: 1122-17-4
      • EINECS Number: 214-343-0
      • Synonyms: Dichloromaleic anhydride,2,3-Dichloromaleic anhydride

      Relevant identified uses of the substance or mixture and uses advised against

      • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
      • Uses advised against: none

      Company Identification

      • Company: Chemicalbook
      • Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
      • Telephone: 400-158-6606

      SECTION 2: Hazards identification

      GHS Label elements, including precautionary statements

      Pictogram(s)
      • Signal wordWarning
      Hazard statement(s)
      H335 May cause respiratory irritation
      H319 Causes serious eye irritation
      H315 Causes skin irritation
      Prevention
      P271 Use only outdoors or in a well-ventilated area.
      P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
      P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
      P264 Wash ... thoroughly after handling.
      Response
      P319 Get medical help if you feel unwell.
      P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
      P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
      P362+P364 Take off contaminated clothing and wash it before reuse.
      P332+P317 If skin irritation occurs: Get medical help.
      P321 Specific treatment (see ... on this label).
      P302+P352 IF ON SKIN: Wash with plenty of water/...
      Storage
      P405 Store locked up.
      P403+P233 Store in a well-ventilated place. Keep container tightly closed.
      Disposal
      P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

      SECTION 3: Composition/information on ingredients

      Substance

      • Product name: Dichloromaleic anhydride
      • Synonyms: Dichloromaleic anhydride,2,3-Dichloromaleic anhydride
      • CAS: 1122-17-4
      • EC number: 214-343-0
      • MF: C4Cl2O3
      • MW: 166.95

      SECTION 4: First aid measures

      Description of first aid measures

      If inhaled
      If breathed in, move person into fresh air. If not breathing, give artificial respiration.
      In case of skin contact
      Wash off with soap and plenty of water.
      In case of eye contact
      Flush eyes with water as a precaution.
      If swallowed
      Never give anything by mouth to an unconscious person. Rinse mouth with water.

      Most important symptoms and effects, both acute and delayed

      The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

      Indication of any immediate medical attention and special treatment needed

      No data available

      SECTION 5: Firefighting measures

      Extinguishing media

      Suitable extinguishing media
      Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

      Special hazards arising from the substance or mixture

      Carbon oxides, Hydrogen chloride gas

      Advice for firefighters

      Wear self-contained breathing apparatus for firefighting if necessary.

      Further information

      No data available

      SECTION 6: Accidental release measures

      Personal precautions, protective equipment and emergency procedures

      Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8.

      Environmental precautions

      No special environmental precautions required.

      Methods and materials for containment and cleaning up

      Sweep up and shovel. Keep in suitable, closed containers for disposal.

      Reference to other sections

      For disposal see section 13.

      SECTION 7: Handling and storage

      Precautions for safe handling

      Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

      Conditions for safe storage, including any incompatibilities

      Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive.

      Specific end use(s)

      Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

      SECTION 8: Exposure controls/personal protection

      control parameter

      Hazard composition and occupational exposure limits
      Does not contain substances with occupational exposure limits.

      Exposure controls

      Appropriate engineering controls

      General industrial hygiene practice.

      Personal protective equipment
      Eye/face protection

      Use equipment for eye protection tested and approved under appropriate

      government standards such as NIOSH (US) or EN 166(EU).

      Skin protection

      Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

      The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

      Full contact

      Material: Nitrile rubber

      Minimum layer thickness: 0,11 mm Break through time: 480 min

      Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

      Splash contact Material: Nitrile rubber

      Minimum layer thickness: 0,11 mm Break through time: 480 min

      Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

      data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

      If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

      Body Protection

      Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

      Respiratory protection

      Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

      Control of environmental exposure

      No special environmental precautions required.

      SECTION 9: Physical and chemical properties

      Information on basic physicochemical properties

      • Appearancebeige crystalline
      • OdourNo data available
      • Odour ThresholdNo data available
      • pHNo data available
      • Melting point/freezing pointMelting point/range: 120 °C
      • Initial boiling point and boiling range118-125 °C
      • Flash pointNo data available
      • Evaporation rateNo data available
      • Flammability (solid, gas)No data available
      • Upper/lower flammability or explosive limitsNo data available
      • Vapour pressureNo data available
      • Vapour densityNo data available
      • Relative densityNo data available
      • Water solubilityNo data available
      • Partition coefficient: n-octanol/waterNo data available
      • Autoignition temperatureNo data available
      • Decomposition temperatureNo data available
      • ViscosityNo data available
      • Explosive propertiesNo data available
      • Oxidizing propertiesNo data available

      Other safety information

      No data available

      SECTION 10: Stability and reactivity

      Reactivity

      No data available

      Chemical stability

      Stable under recommended storage conditions.

      Possibility of hazardous reactions

      No data available

      Conditions to avoid

      No data available

      Incompatible materials

      Strong oxidizing agents, acids, Bases, Alcohols, Amines

      Hazardous decomposition products

      Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas

      Other decomposition products - No data available In the event of fire: see section 5

      SECTION 11: Toxicological information

      Information on toxicological effects

      Acute toxicity
      No data available
      Skin corrosion/irritation
      No data available
      Serious eye damage/eye irritation
      No data available
      Respiratory or skin sensitisation
      No data available
      Germ cell mutagenicity
      No data available
      Carcinogenicity
      IARC: No component of this product present at levels greater than or equal to 0.1% is
      identified as probable, possible or confirmed human carcinogen by IARC.
      Reproductive toxicity
      No data available
      Specific target organ toxicity - single exposure
      No data available
      Specific target organ toxicity - repeated exposure
      No data available
      Aspiration hazard
      No data available
      Additional Information
      RTECS: Not available
      To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

      SECTION 12: Ecological information

      Toxicity

      No data available

      Persistence and degradability

      No data available

      Bioaccumulative potential

      No data available

      Mobility in soil

      No data available

      Results of PBT and vPvB assessment

      This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

      Other adverse effects

      No data available

      SECTION 13: Disposal considerations

      Waste treatment methods

      Product

      Offer surplus and non-recyclable solutions to a licensed disposal company.

      Contaminated packaging

      Dispose of as unused product.

      SECTION 14: Transport information

      UN number

      ADR/RID: - IMDG: - IATA: -

      14.2

      UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods


      14.3

      Transport hazard class(es)

      ADR/RID: - IMDG: -


      IATA: -

      14.4

      Packaging group

      ADR/RID: - IMDG: -


      IATA: -

      14.5

      Environmental hazards

      ADR/RID: no IMDG Marine pollutant: no


      IATA: no

      14.6

      Special precautions for user

      No data available


      SECTION 15: Regulatory information

      Safety, health and environmental regulations/legislation specific for the substance or mixture

      Regulations on the Safety Management of Hazardous Chemicals
      China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/
      Measures for Environmental Management of New Chemical Substances
      European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/
      New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/
      Philippines Inventory of Chemicals and Chemical Substances (PICCS):Not Listed. website: https://emb.gov.ph/
      Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/
      Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr
      Vietnam National Chemical Inventory:Not Listed. website: https://chemicaldata.gov.vn/
      EC Inventory:Listed.
      United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

      SECTION 16: Other information

      Abbreviations and acronyms

      • CAS: Chemical Abstracts Service
      • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
      • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
      • IMDG: International Maritime Dangerous Goods
      • IATA: International Air Transportation Association
      • TWA: Time Weighted Average
      • STEL: Short term exposure limit
      • LC50: Lethal Concentration 50%
      • LD50: Lethal Dose 50%
      • EC50: Effective Concentration 50%

      References

      【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

      【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

      【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

      【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

      【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

      【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

      【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

      【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

      【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

      【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

      Disclaimer:

      The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.

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