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Chemical & pharmaceutical bulletin

Chemical & pharmaceutical bulletin

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The Mechanism for the Reaction of Biguanides with Diethyl Oxalate

Published:25 March 1968 DOI: 10.1248/CPB.16.471
S. Hayashi,?M. Furukawa,?J. Yamamoto,?Y. Nishizima

Abstract

The intermediate products yielded by the reaction of biguanides with diethyl oxalate were inferred to be (4, 5-dioxo-2-imidazolidinylidene) guanidines by means of their infrared absorption spectra. Moreover, in order to elucidate this reaction mechanism, the reaction between guanidine containing the similar structural moiety to biguanides and diethyl oxalate was examined. As the result, it was assumed that the reaction of biguanide with diethyl oxalate would proceed through the cyclic transition state to afford (4, 5-dioxo-2-imidazolidinylidene) guanidine.

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Related products
Procduct Name CAS Molecular Formula Supplier Price
Diethyl oxalate 95-92-1 C6H10O4 476 suppliers $5.00-$1000.00
N-(4-FLUORO-PHENYL)-GUANIDINE 65783-21-3 C7H8FN3 26 suppliers $75.00-$2134.00
GUANIDINE 90332-86-8 CH3N3O 10 suppliers Inquiry
Biguanides 0 suppliers Inquiry

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