N-乙基-N-芐基苯胺(92-59-1)質(zhì)譜(MS)
InChI:InChI=1S/C15H17N/c1-2-16(15-11-7-4-8-12-15)13-14-9-5-3-6-10-14/h3-12H,2,13H2,1H3
InChIKey: HSZCJVZRHXPCIA-UHFFFAOYSA-N
Smiles:C1(CN(CC)C2=CC=CC=C2)=CC=CC=C1
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Mass
MS-NW-8491
N-ethyl-N-phenylbenzylamine
C15H17N (Mass of molecular ion: 211)
Source Temperature: 260 °C
Sample Temperature: 140 °C
Reservoir, 75 eV
27.0 1.8
28.0 1.2
29.0 1.8
39.0 4.3
41.0 1.4
50.0 1.2
51.0 7.3
52.0 1.3
63.0 2.0
64.0 1.0
65.0 11.0
77.0 16.5
78.0 2.4
79.0 1.7
89.0 1.5
91.0 100.0
92.0 8.5
104.0 5.8
105.0 2.0
106.0 4.6
118.0 1.2
120.0 1.7
134.0 7.6
180.0 1.6
182.0 1.2
196.0 17.0
197.0 2.7
210.0 1.6
211.0 22.7
212.0 3.9
400 MHz in CDCl3
90 MHz in CDCl3
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| 1H NMR |
399.65 MHz |
| C15 H17 N
|
0.05 ml : 0.5 ml CDCl3
|
| N-ethyl-N-phenylbenzylamine
|
 |
Assign. Shift(ppm)
A 7.258
B 7.207
C 7.18
D 7.15
E 6.66
F 6.64
G 4.461
J 3.418
K 1.159
|
Hz ppm Int.
2909.91 7.282 97
2908.81 7.279 138
2907.35 7.275 69
2902.34 7.263 247
2901.49 7.261 329
2900.51 7.258 249
2896.36 7.248 134
2894.41 7.243 380
2883.30 7.215 418
2876.34 7.198 298
2871.46 7.185 87
2869.38 7.180 190
2865.72 7.171 157
2864.01 7.167 141
2862.18 7.162 93
2861.57 7.161 97
2859.01 7.154 348
2857.30 7.150 367
2854.98 7.144 67
2852.17 7.137 115
2850.10 7.132 312
2847.66 7.126 49
2669.68 6.681 294
2668.70 6.678 396
2661.74 6.661 284
2660.77 6.658 445
2659.79 6.656 374
2657.35 6.650 61
2654.54 6.643 168
2653.56 6.640 253
2647.22 6.624 83
2646.24 6.622 124
2645.39 6.620 70
1783.08 4.462 674
1376.71 3.445 148
1369.63 3.428 419
1362.55 3.410 420
1355.47 3.392 149
470.46 1.178 556
463.38 1.160 1000
459.47 1.150 41
456.30 1.142 533
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| 1H NMR |
89.56 MHz |
| C15 H17 N
|
0.04 ml : 0.5 ml CDCl3
|
| N-ethyl-N-phenylbenzylamine
|
|
Assign. Shift(ppm)
A 7.25
B 7.16
C 6.76
D 6.65
E 4.495
F 3.434
G 1.186
|
Hz ppm Int.
652.38 7.285 79
652.25 7.283 79
651.81 7.278 80
650.88 7.268 163
649.00 7.247 1000
645.50 7.208 89
643.63 7.187 118
642.06 7.170 150
641.38 7.162 226
639.38 7.140 39
637.31 7.117 51
634.38 7.084 172
605.25 6.759 35
602.44 6.727 304
600.13 6.701 61
595.31 6.648 181
594.69 6.641 187
593.63 6.629 129
589.19 6.579 31
588.00 6.566 47
402.63 4.496 410
319.69 3.570 60
312.63 3.491 194
305.63 3.413 208
298.50 3.333 72
113.06 1.263 290
106.06 1.185 583
99.00 1.106 248