二苯甲酮腙(5350-57-2)紅外圖譜(IR2)

產(chǎn)品名稱:二苯甲酮腙

CAS:5350-57-2

分子式:C13H12N2

分子量: 196.25

InChI:InChI=1S/C13H12N2/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,14H2

InChIKey: QYCSNMDOZNUZIT-UHFFFAOYSA-N

Smiles:C(=N/N)(/C1=CC=CC=C1)\C1=CC=CC=C1

Mass

MS-NW-9495          
benzophenone hydrazone
C13H12N2            (Mass of molecular ion:    196)

   Source Temperature: 150 °C
   Sample Temperature:  80 °C
   Direct, 75 eV

      18.0       2.2
      28.0       1.1
      39.0       2.0
      50.0       2.4
      51.0      11.3
      52.0       1.1
      63.0       2.5
      65.0       2.6
      66.0       2.4
      69.5       1.1
      74.0       1.2
      75.0       1.5
      76.0       4.2
      77.0      38.6
      78.0       3.3
      82.0       1.9
      82.5       2.2
      83.0       1.1
      83.5       1.3
      89.0       1.5
      91.0       3.0
      92.0       5.2
      93.0       9.1
      98.0       1.6
     103.0       2.0
     104.0       1.9
     115.0       1.8
     118.0       6.5
     119.0      11.2
     139.0       2.1
     151.0       2.3
     152.0       4.8
     153.0       1.7
     163.0       2.1
     164.0       2.5
     165.0      36.6
     166.0       7.4
     167.0       2.5
     168.0       1.5
     178.0       5.4
     179.0      11.8
     180.0      20.7
     181.0       3.6
     195.0      37.3
     196.0     100.0
     197.0      15.3
     198.0       1.0

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₃ H₁₂ N₂	0.041 g : 0.5 ml CDCl₃
benzophenone hydrazone

    Assign.     Shift(ppm)

      A             7.510
      B             7.47
      C             7.44
      D             7.28
      E             7.27
      F             7.25
      G             5.42

     Hz     ppm     Int.

   3011.35   7.535    201
   3010.13   7.532    356
   3008.54   7.528    144
   3004.88   7.519    241
   3003.17   7.515    733
   3001.71   7.511    454
   2999.27   7.505     66
   2996.95   7.499    297
   2995.73   7.496    600
   2994.87   7.494    439
   2993.65   7.491    153
   2992.31   7.488     80
   2989.01   7.480    564
   2987.79   7.477    238
   2986.69   7.474    369
   2986.08   7.472    344
   2984.86   7.469    271
   2983.76   7.466    288
   2982.91   7.464    346
   2980.96   7.459    923
   2979.25   7.455    859
   2977.29   7.450    106
   2975.59   7.446    178
   2973.14   7.440    398
   2970.83   7.434    113
   2967.29   7.425     93
   2965.82   7.422    150
   2964.48   7.418     78
   2921.14   7.310     35
   2918.21   7.302    150
   2914.92   7.294    797
   2913.45   7.291    964
   2911.38   7.285    304
   2909.67   7.281    604
   2909.06   7.280    666
   2908.45   7.278    625
   2907.35   7.275    680
   2906.62   7.273    887
   2905.76   7.271    740
   2905.40   7.270    731
   2903.20   7.265   1000
   2901.73   7.261    963
   2898.68   7.254    254
   2898.19   7.252    198
   2896.73   7.249    153
   2892.09   7.237     55
   2890.26   7.232    150
   2167.24   5.423    524

in CDCl3