Mass

MS-NW-3273          
trans-3-hexenoic acid
C6H10O2             (Mass of molecular ion:    114)

   Source Temperature: 260 °C
   Sample Temperature: 180 °C
   Reservoir, 75 eV

      15.0       2.6
      18.0       1.6
      26.0       4.2
      27.0      31.1
      28.0       3.4
      29.0      28.9
      31.0       2.8
      37.0       2.2
      38.0       5.0
      39.0      39.3
      40.0       8.4
      41.0     100.0
      42.0      31.1
      43.0      15.1
      44.0       1.7
      45.0      12.5
      50.0       3.5
      51.0       4.7
      52.0       2.1
      53.0      16.2
      54.0      10.2
      55.0      77.2
      56.0       4.5
      57.0      21.1
      58.0       3.4
      59.0       3.4
      60.0      44.2
      61.0       1.8
      62.0       1.2
      63.0       1.4
      65.0       2.3
      66.0       1.3
      67.0      11.7
      68.0      47.5
      69.0      40.7
      70.0       3.0
      71.0       6.6
      72.0       3.1
      73.0      34.7
      74.0       1.5
      81.0       5.4
      85.0       1.6
      86.0       2.2
      95.0       1.5
      96.0       8.6
      97.0       3.3
      99.0      13.8
     105.0       1.0
     113.0       1.0
     114.0      39.1
     115.0       3.0

Assign. Shift(ppm) A 10.4 B 5.631 C 5.512 D 3.067 E 2.058 F 0.993 ASSIGNED BY C-H COSY.

     Hz     ppm     Int.

   2267.15   5.673     37
   2262.27   5.661     38
   2261.05   5.658     72
   2259.83   5.655     52
   2254.94   5.643     41
   2253.27   5.639     46
   2251.89   5.635     71
   2250.67   5.632     53
   2246.86   5.623     63
   2245.64   5.620    129
   2244.57   5.617     99
   2240.75   5.607     42
   2239.53   5.604     73
   2238.46   5.602     56
   2217.25   5.548     38
   2215.88   5.545     72
   2214.51   5.542     53
   2210.54   5.532     75
   2209.17   5.528    144
   2207.64   5.524    101
   2203.83   5.515     44
   2202.30   5.511     78
   2200.62   5.507     81
   2199.10   5.503     44
   2195.28   5.494     42
   2193.76   5.490     84
   2192.23   5.486     60
   2186.89   5.473     45
   2185.36   5.469     32
   1231.69   3.082    118
   1230.47   3.079    287
   1229.25   3.076    349
   1228.18   3.074    226
   1224.82   3.065    140
   1223.60   3.062    299
   1222.38   3.059    354
   1221.47   3.057    233
    837.86   2.097     38
    836.64   2.094     45
    835.57   2.091     40
    831.60   2.081     81
    830.38   2.078    142
    829.16   2.075    147
    827.94   2.072     97
    825.50   2.066     74
    824.13   2.063    155
    822.91   2.060    228
    821.69   2.057    203
    818.02   2.047     77
    816.80   2.044    136
    815.43   2.041    170
    814.21   2.038    129
    810.55   2.029     35
    809.33   2.026     49
    808.11   2.023     50
    806.88   2.019     34
    404.36   1.012    531
    396.88   0.994   1000
    389.40   0.975    540