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Product Name:(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-diMesitylethylenediaMinato Cobalt(II)
CAS:361346-80-7
Package:100MG
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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Product Name:(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-diMesitylethylenediaMinato Cobalt(II)
CAS:361346-80-7
Package:100Mg Remarks:B2314
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TCI (Shanghai) Development Co., Ltd.
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Product Name:(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
CAS:361346-80-7
Package:100MG
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Energy Chemical
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Product Name:(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
CAS:361346-80-7
Package:100MG
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| | (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Basic information |
| Product Name: | (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | | Synonyms: | (R)-AMAC;(R,R)-AMAC;(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate;(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) | | CAS: | 361346-80-7 | | MF: | C32H38CoN2O4 | | MW: | 573.59 | | EINECS: | | | Product Categories: | Asymmetric Synthesis;Catalysts for Organic Synthesis;Classes of Metal Compounds;Co (Cobalt) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds | | Mol File: | 361346-80-7.mol |  |
| | (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties |
| Melting point | 246-250°C | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | solid | | optical activity | [α]/D 291°, c = 0.1 in chloroform |
| | (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Usage And Synthesis |
| Uses | - Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds
Catalyst for:
- Enantioselective borohydride reduction
- Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
- Stereoselective borohydride reduction of diketones to diols
- Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
- Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
- Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
- Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones
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| | (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Preparation Products And Raw materials |
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