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| | N-TERT-BUTYLTRIMETHYLSILYLAMINE Basic information |
| | N-TERT-BUTYLTRIMETHYLSILYLAMINE Chemical Properties |
| Boiling point | 118-119 °C(lit.) | | density | 0.762 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.406(lit.) | | Fp | 80 °F | | form | liquid | | pka | 13.25±0.70(Predicted) | | color | Clear, colourless | | BRN | 1734528 |
| Hazard Codes | C | | Risk Statements | 10-34 | | Safety Statements | 16-26-36/37/39-45 | | RIDADR | UN 2733 3/PG 3 | | WGK Germany | 3 | | F | 10-21 | | HazardClass | 3.2 | | PackingGroup | III | | HS Code | 2931900090 |
| | N-TERT-BUTYLTRIMETHYLSILYLAMINE Usage And Synthesis |
| Uses | N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates. | | Preparation |
N-tert-Butyltrimethylsilylamine is prepared by the reaction of the parent amines with n-Butyllithium in THF/hexane. The parent amines are prepared by the reaction of lithium t-butylamide and the corresponding chlorosilanes (eq 1).
| | General Description | N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3). | | storage |
N-tert-Butyltrimethylsilylamine reacts readily with protic solvents, especially water, and must be maintained in a dry environment. It is thermally stable. Use in a fume hood.
| | Purification Methods |
Best purified by distillation.
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| | N-TERT-BUTYLTRIMETHYLSILYLAMINE Preparation Products And Raw materials |
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