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???? ????? ??? ???
?? ??:
10026-17-2
???:
???? ?????
???(??):
?????????;?????????(?????????);?????????(?????????)(COBALTOUSFLUORIDE);???(II)???
???:
Cobalt(II) fluoride
???(??):
difluorocobalt;COBALT FLUORIDE;Cobalt(Ⅱ)fluorde;Cobalt(Ⅱ)fluoride;COBALT DIFLUORIDE;COBALTOUS FLUORIDE;COBALT(II) FLUORIDE;Two cobalt fluoride;COBALT FLUORIDE PINK;cobaltfluoride(cof2)
CBNumber:
CB7681660
???:
CoF2
??? ??:
96.93
MOL ??:
10026-17-2.mol
MSDS ??:
SDS

???? ????? ??

???
1200 °C
?? ?
1400 °C
??
4.46 g/mL at 25 °C
???
soluble in acid solutions
??? ??
??
Specific Gravity
4.46
??
???
???
?, ???, ???? ?????.
??
Hygroscopic
Crystal Structure
Rutile type
crystal system
square
Merck
14,2440
Space group
P42/mnm
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.46950.46950.31829090900.0701
?? ??
ACGIH: TWA 0.02 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
???
???
CAS ??????
10026-17-2(CAS DataBase Reference)
EPA
Cobalt fluoride (CoF2) (10026-17-2)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,C
?? ???? ?? 25-34
????? 26-36/37/39-45-50A-28A
????(UN No.) UN 2923 8/PG 3
WGK ?? 3
RTECS ?? GG0770000
F ?????? 21
?? ?? ?? Toxic
TSCA Yes
?? ?? 6.1
???? III
HS ?? 28261990
?? ?? ??? 10026-17-2(Hazardous Substances Data)
???? ?? KE-06097
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
3 0

???? ????? MSDS


Cobalt difluoride

???? ????? C??? ??, ??, ??

??? ??

Rose-red crystals or powder. Soluble in cold water and hydrofluoric acid. Decomposes in hot water. Ammine complexes can be prepared from the hydrate.

??? ??

Red tetragonal crystal; density 4.46 g/cm3; melts at 1,127°C; vaporizes around 1,400°C; sparingly soluble in water; soluble in warm mineral acids; decomposes in boiling water. Tetrahydrate is red orthogonal crystal; density 2.22 g/cm3; decomposes on heating; soluble in water; di- and trihydrates are soluble in water.

??

Cobalt(II) fluoride can be used as a catalyst to alloy metals. It is also used for optical deposition, of which it tremendously improves optical quality. The compound may be used in dental care.

?? ??

Violet to red solid. Sinks and mixes slowly with water.

?? ???

Cobalt(II) fluoride is a toxic, light brown crystalline material, when exposed to water Cobalt(II) fluoride forms highly corrosive hydrofluoric acid. When heated to decomposition Cobalt(II) fluoride emits toxic fumes of metallic cobalt and fluorides [Lewis, 3rd ed., 1993, p. 344].

???

Highly toxic.

????

INHALATION: Inhalation of dust may cause pulmonary symptoms. EYES: Irritation. SKIN: Skin rashes, dermatitis. INGESTION: Nausea and vomiting caused by local irritation.
LD50 oral (rat): 150 mg/kg

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of Co and F-.

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