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ChemicalBook >?? ???? >(1R,2R)-(+)-N-(4-??????)-1,2-??????????

(1R,2R)-(+)-N-(4-??????)-1,2-??????????

(1R,2R)-(+)-N-(4-??????)-1,2-??????????

(1R,2R)-(+)-N-(4-??????)-1,2-?????????? ??? ???

?? ??:: 174291-96-4

???:: (1R,2R)-(+)-N-(4-??????)-1,2-??????????

???(??):: (1R,2R)-(+)-N-(4-??????)-1,2-??????????

???:: (1R,2R)-(+)-N-(4-TOLUENESULPHONYL)-1,2-DIAMINOCYCLOHEXANE

???(??):: (-)-TsCYDN;(R,R)-Ts-CDA;(1R,2R)-N-p-Tosyl-1,2-cyclohexanediamine,99%e.e.;(1R,2R)-(-)-N-p-Tosyl-1,2-cyclohexanediamine 97%;N-((1R,2R)-2-amin℃yclohexyl)-4-methylbenzenesulfonamide;(1R,2R)-(+)-N-(4-TOLUENESULPHONYL)-1,2-DIAMINOCYCLOHEXANE;Benzenesulfonamide, N-[(1R,2R)-2-aminocyclohexyl]-4-methyl-;(1R,2R)-(?)-N-p-Tosyl-1,2-cyclohexanediamine

CBNumber:: CB7511387

???:: C13H20N2O2S

??? ??:: 268.38

MOL ??:: 174291-96-4.mol

??

??

??

?? ?? 38

(1R,2R)-(+)-N-(4-??????)-1,2-?????????? ??

???: 105-109°C

?? ?: 417.4±55.0 °C(Predicted)

??: 1.23±0.1 g/cm3(Predicted)

?? ??: Keep in dark place,Inert atmosphere,Room temperature

??? ??: solid

?? ?? (pKa): 11.69±0.40(Predicted)

optical activity: [α]22/D -41.0, c = 1 in chloroform

??

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xn
?? ???? ??	22-36/37/38
WGK ??	3

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	?? ??	P- ??
H302	??? ???	?? ?? ?? - ??	?? 4	??		P264, P270, P301+P312, P330, P501
H315	??? ??? ???	????? ?? ?????	?? 2	??		P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??		P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

(1R,2R)-(+)-N-(4-??????)-1,2-?????????? C??? ??, ??, ??

??

Chiral ligand for asymmetric transfer hydrogen.

(1R,2R)-(+)-N-(4-??????)-1,2-?????????? ?? ?? ? ???

???

?? ??

(1R,2R)-(+)-N-(4-??????)-1,2-?????????? ?? ??

???( 38)?? ??

???	??	???	??	?? ?	??
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(1R,2R)-(+)-N-(4-??????)-1,2-?????????? ?? ??:

(1R,2R)-(+)-N,N'-DI-P-TOSYL-1,2-CYCLOHEXANEDIAMINE CIS-(1S,2R)-1N-CBZ-CYCLOHEXANE-1,2-DIAMINE (1S,2S)-Boc-1,2-diaminocyclohexane CIS-(1R,2S)-1N-CBZ-CYCLOHEXANE-1,2-DIAMINE (1R,2R)-N-Methylsulfonyl-1,2-diphenylethanediamine, 98+% (1R,2R)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE N-Boc-(1S, 2R)-diaminocyclohexane (R)-Hydroxyphenylaceticacid salt||| (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1S,2S)-(-)-N-(4-TOLUENESULPHONYL)-1,2-DIAMINOCYCLOHEXANE (1S,2S)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine (R)-(+)-a,a-Diphenyl-2-pyrrolidinemethanol (1S,2S)-(-)-N,N-DI-P-TOSYL-1,2-CYCLOHEXANEDIAMINE

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