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7773-06-0
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???(??):
????????;???????;?????;???,??????;????XSULFAMICACID,AMMONIUMSALT;????????;?????????;???;???;???????;????????;????????;??? ?????
???:
Ammonium sulfamate
???(??):
AMS;AMMONIUM AMIDOSULFATE;Sulfamate;SULFAMIC ACID AMMONIUM SALT;Ammat;Amcide;Ammate;Ikurin;famate;Amicide
CBNumber:
CB4344641
???:
H6N2O3S
??? ??:
114.12
MOL ??:
7773-06-0.mol
MSDS ??:
SDS

??????? ??

???
131-135 °C (lit.)
?? ?
160°C
?? ??
680kg/m3
??
1.769
???
0Pa at 20℃
???
160°C
?? ??
no restrictions.
???
H2O: 1 M at 20 °C, ??, ??
??? ??
??? ??
??
???
??????(pH)
5.0-6.0 (50g/l, H2O, 20℃)
??
??? ?? ??
pH ??
4.5 - 6.0
???
1950g/L(20℃)
??
Air & Moisture Sensitive
Merck
14,554
?? ??
ACGIH: TWA 10 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
NIOSH: IDLH 1500 mg/m3; TWA 10 mg/m3; TWA 5 mg/m3
???
????. ??, ????? ???? ????.
InChIKey
GEHMBYLTCISYNY-UHFFFAOYSA-N
LogP
-4.34 at 20℃
CAS ??????
7773-06-0(CAS DataBase Reference)
NIST
Ammonium sulfamate(7773-06-0)
EPA
Ammonium sulfamate (7773-06-0)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn,N
?? ???? ?? 22-50
????? 24/25-22-61
OEB B
OEL TWA: 10 mg/m3 (total)
WGK ?? 1
RTECS ?? WO6125000
F ?????? 3-10
TSCA Yes
HS ?? 29222100
?? ?? ??? 7773-06-0(Hazardous Substances Data)
?? LD50 orally in rats: 3.0 g/kg (Ambrose)
IDLA 1,500 mg/m3
???? ?? KE-01742
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
H336 ?? ?? ???? ??? ? ?? ?????? ?? ??(1? ??);???? ?? 3 ?? P261, P271, P304+P340, P312,P403+P233, P405, P501
H400 ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? GHS hazard pictograms P273, P391, P501
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P330 ?? ?????.
P403+P233 ??? ??? ? ?? ?? ??? ???? ?????.
P405 ???? ?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
1 0
OX

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Ammonium sulfamate is a white to yellow crystalline solid.

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Ammonium sulfamate (AMS) is an inorganic herbicide used for control of woody plants and herbaceous perennials.

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Ammonium sulfamate is a white crystalline solid. Ammonium sulfamate is soluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Ammonium sulfamate is used to flameproof fabrics and papers, in weed or brush killing products, and for other uses.

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Water soluble. Hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid)] .

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Ammonium sulfamate is incompatible with the following: Acids, hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid).] .

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Hot acid solutions when enclosed may explode.

????

Inhalation causes irritation of nose and throat. Ingestion causes gastrointestinal disturbances. Dust irritates eyes.

????

Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fires.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Somewhat explosive when heated or by spontaneous chemical reaction in a hot acid solution. A powerful oxidizer. When heated to decomposition it emits very toxic fumes of NH3, NOx, and SOx. See also SULFONATES and SULFAMIC ACID.

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Ammonium sulfamate is used as a herbicide and in compositions for retarding flame in textiles and paper products; a softener for paper, cotton textiles.

Carcinogenicity

The oral LD50 values were 3900 mg/kg for rats and 5760 mg/kg for mice.

?? ??

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise it from water at room temperature (1mL/g) by adding EtOH and cooling. [Sisler & Audrieth Inorg Synth II 180 1946.]

? ???

Strong oxidizers, potassium, potassium chlorate, sodium nitrite, metal chlorates, and hot acid solutions. Elevated temperatures cause a highly exothermic reaction with water.

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Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Dilute with water, make neutral with acid or base and flush into sewer with more water.

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