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1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE&

1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& ??? ???
?? ??:
122296-00-8
???:
1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE&
???(??):
benzotriazol-1-ylmethyl(trimethyl)silane;1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE 99%;1H-Benzotriazole, 1-[(trimethylsilyl)methyl]-;1-[(Trimethylsilyl)Methyl]-1H-1,2,3-Benzotriazole;1-((Trimethylsilyl)methyl)-1H-benzo[d][1,2,3]triazole
CBNumber:
CB3505157
???:
C10H15N3Si
??? ??:
205.33
MOL ??:
122296-00-8.mol

1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& ??

???
56-60 °C(lit.)
?? ?
300.3±25.0 °C(Predicted)
??
1.06±0.1 g/cm3(Predicted)
???
???? ????? ? ?????.
?? ?? (pKa)
1.44±0.30(Predicted)
??? ??
solid
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 22-36/37/38
????? 26-36
WGK ?? 3
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& C??? ??, ??, ??

??? ??

mp 55–56 °C.

??

1-[(Trimethylsilyl)methyl]- 1H-benzotriazole is a reagent in the preparation of ketones, carboxylic acids,One-carbon Homologation of Carboxylic Acids,Synthesis of Fused Heterocycles and fused heterocycles.

?? ??

1-[(trimethylsilyl)methyl]-1H-benzotriazole is readily prepared in a reaction of sodium benzotriazolide with chloromethyltrimethylsilane.

1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& ?? ?? ? ???

???

?? ??


1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& ?? ??

???( 22)?? ??
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1-((TRIMETHYLSILYL)METHYL)BENZOTRIAZOLE& ?? ??:

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