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??????

??????
?????? ??? ???
?? ??:
123-90-0
???:
??????
???(??):
??????
???:
Thiomorpholine
???(??):
thiazinane;1,4-Thiazane;TETRAHYDRO-2H-1,4-THIAZINE;1,4-Thiazan;Parathiazan;ThiomorphoL;hiomorpholine;THIAMORPHOLINE;THIOMORPHOLINE;thiazolidinane
CBNumber:
CB3266519
???:
C4H9NS
??? ??:
103.19
MOL ??:
123-90-0.mol
MSDS ??:
SDS

?????? ??

???
166-168
?? ?
169 °C (lit.)
??
1.026 g/mL at 25 °C (lit.)
???
n20/D 1.538(lit.)
???
140 °F
?? ??
under inert gas (nitrogen or Argon) at 2–8 °C
???
?? ??: ??? ?? ? ???? (lit.)
?? ?? (pKa)
9.14±0.20(Predicted)
??? ??
??? ??
??
Colorless to Light yellow to Light orange
???
?? ?? ??? ? ?? ??? ?? ??.
??
Air Sensitive
Merck
14,9300
BRN
102550
InChIKey
BRNULMACUQOKMR-UHFFFAOYSA-N
CAS ??????
123-90-0(CAS DataBase Reference)
NIST
Thiomorpholine(123-90-0)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C,Xi
?? ???? ?? 34-37-36/37/38-R37-R34
????? 26-36/37/39-45-36-S45-S36/37/39-S26
????(UN No.) UN 3267 8/PG 3
WGK ?? 3
F ?????? 10-13-23
?? ?? ?? Irritant
?? ?? 8
???? III
HS ?? 29349990
????(GHS): GHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P280 ????/???/???/?????? ?????.
P301+P330+P331 ???? ?? ?????. ??? ?? ?? ???.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P501 ...? ??? / ??? ?? ???.
NFPA 704
1
3 0

?????? MSDS


Thiomorpholine

?????? C??? ??, ??, ??

??? ??

Clear colorless to yellow liquid

??

Thiomorpholine is used as an intermediate for blonanserin. It is used in the preparation of pyrrole derivatives, which acts as a antimycobacterial agent. It is further involved in the hypocholesterolemic activity.

??

ChEBI: A saturated organic heteromonocyclic parent that is an analogue of morpholine where the oxygen atom is replaced by sulfur.

?? ??

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Purification Methods

Purify it by vacuum distillation. The hydrochloride has m 179o (from isoPrOH or EtOH/Et2O/HCl). [Davies J Chem Soc 306 1920, Beilstein 27 II 4, 2 III/IV 636.]

?????? ?? ?? ? ???

???

?????(9???) ????? ?? ?? ???? ??????(??) Bis(2-chloroethyl)amine hydrochloride ?????? ????

?? ??

N-???????????? ??????-1,1-????? 4-(thiomorpholin-4-yl)benzonitrile 4-(4-?????)?????? N-(2-????????)?????? 4-Methylthiomorpholine 4-(4-?????)??????

?????? ?? ??

???( 270)?? ??
??? ?? ??? ?? ?? ? ??
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