Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions
Asymmetrical aldol reactions with a-chiral aldehydes
Addition reaction with α-pinene
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Monochloroborane-dimethyl sulfide is prepared by redistribution of Borane-Dimethyl Sulfide (BMS) and Boron Trichloride. SMe2 and by the reaction of BMS with CCl4. The reagent is in equilibrium with approximately 15% each of BHCl2.SMe2 and BMS.