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1,3-Diphenylacetone

1,3-Diphenylacetone ??? ???
?? ??:
102-04-5
???:
1,3-Diphenylacetone
???(??):
1,3-DIPHENYLPROPAN-2-ONE;1,3-DIPHENYL-2-PROPANONE;FEMA 2397;-2-propanone;BENZYL KETONE;DIBENZYL KETONE;Twobenzyl ketone;Diphenylpropanone;1,3-DIPHENYLACETONE;sym-Diphenylacetone
CBNumber:
CB0665274
???:
C15H14O
??? ??:
210.27
MOL ??:
102-04-5.mol
MSDS ??:
SDS

1,3-Diphenylacetone ??

???
32-34 °C(lit.)
?? ?
330 °C(lit.)
??
1.04
???
1.5725 (estimate)
FEMA
2397 | 1,3-DIPHENYL-2-PROPANONE
???
>230 °F
?? ??
Keep in dark place,Sealed in dry,Room Temperature
???
?????(?? ???), ???(?? ???)
??? ??
?? ?? ??? ??
??
?? ???
??
????? ??? ? 10.00%. ? ?, ???, ??????, ???? ??
?? ??
?? ??
???
?? ?? ?????.
JECFA Number
832
BRN
974767
???
????. ?? ??. ?? ???? ???? ????.
LogP
3.18
CAS ??????
102-04-5(CAS DataBase Reference)
NIST
2-Propanone, 1,3-diphenyl-(102-04-5)
EPA
2-Propanone, 1,3-diphenyl- (102-04-5)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????? 24/25-22
WGK ?? 3
RTECS ?? EC2030000
TSCA Yes
HS ?? 29143990
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
1 0

1,3-Diphenylacetone MSDS


1,3-Diphenylacetone

1,3-Diphenylacetone C??? ??, ??, ??

??? ??

White crystals or colorless crystalline mass. M.P. 40°C. B.P. 331°C.
1,3-Diphenylacetone is almost insoluble in water, soluble in alcohol and oils, poorly in Propylent glycol. Sweet, but rathtr faint, fruity-almondy odor of considerable tenacity.

??

1,3-Diphenylacetone is used in the aldol condensation reaction with benzil (a dicarbonyl) and base to create tetraphenylcyclopentadienone.

?? ??

By heating α,?α’-phenyl benzyl ethylene glycol or α,?α’-phenyl benzyl ethylene oxide in the presence of diluted H2SO4 or ZnCl2; also by dry distillation of phenylacetate and magnesium chloride (C6H5CH2COOMgCl) or other salts of phenylacetic acid.

Purification Methods

Fractionally crystallise it from its melt, then crystallise it from pet ether. Store it in the dark. [Beilstein 7 IV 1420.]

1,3-Diphenylacetone ?? ?? ? ???

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1,3-Diphenylacetone ?? ??

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1,3-Diphenylacetone ?? ??:

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