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ChemicalBook >> CAS DataBase List >>9-BBN TRIFLATE

9-BBN TRIFLATE

CAS No.
62731-43-5
Chemical Name:
9-BBN TRIFLATE
Synonyms
9-BBN·CF3SO3;9-BBN TRIFLATE;9-bbn triflate solution;9-BBN Triflate solution 0.5 M in hexanes;9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES;9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E;9-Borabicyclononyl Trifluoromethanesulfonate;9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE;9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate;9-Borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate
CBNumber:
CB2303895
Molecular Formula:
C9H14BF3O3S
Molecular Weight:
270.07
MDL Number:
MFCD00167981
MOL File:
62731-43-5.mol
Last updated:2025-01-27 09:38:02

9-BBN TRIFLATE Properties

Boiling point 265.7±50.0 °C(Predicted)
Density 0.733 g/mL at 25 °C
Flash point -22 °C
solubility sol common inert organic solvents such as Et2O, CH2Cl2, and hexane.
form liquid
BRN 995656
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H225-H304-H315-H336-H361f-H373-H411
Precautionary statements  P201-P210-P273-P301+P310-P308+P313-P331
Hazard Codes  F,C,N,Xn
Risk Statements  11-34-48/20-51/53-62-65-67-38
Safety Statements  16-26-36/37/39-45-61-62-36/37
RIDADR  UN 2924 3/PG 2
WGK Germany  3
F  1-10
HS Code  29349990

9-BBN TRIFLATE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 253138 9-BBN triflate solution 0.5 M in hexanes 62731-43-5 100ml $277 2023-01-07 Buy
Product number Packaging Price Buy
253138 100ml $277 Buy

9-BBN TRIFLATE Chemical Properties,Uses,Production

Uses

Reactant for:

  • Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
  • Mukaiyama aldol addition
  • Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
  • Preparation of palladium porphyrin complexes
  • Boron-mediated β-alkoxy Me ketone aldol addition reactions

  • Enolization agent

Application

9-Bbn triflate can be used to prepare Lewis acids of vinyloxyboranes and boryl nitrify salts; a catalyst for the coupling of silyl enol ethers and acetals; and a catalyst for the isomerization of epoxides to allyl alcohols.

Preparation

Equimolar amounts of 9-Borabicyclo[3.3.1]nonane and Trifluoromethanesulfonic Acid are mixed in hexane and stirred at 20 °C for 24 h after which time 9-BBN TRIFLATE is isolated by vacuum distillation.

reaction suitability

reagent type: reductant

storage

Use in a fume hood; the neat liquid as well as solutions are moisture and air  sensitive; therefore the material should be stored and transferred under a dry inert atmosphere.

1493-13-6
280-64-8
62731-43-5
Synthesis of 9-BBN TRIFLATE from Trifluoromethanesulfonic acid and 9-Borabicyclo[3.3.1]nonane

9-BBN TRIFLATE Preparation Products And Raw materials

Global( 45)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29730 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29860 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49732 58
SIMAGCHEM CORP 		+86-13806087780 sale@simagchem.com China 17365 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Mainchem Co., Ltd. 		-- sarah@mainchem.com China 6567 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 sales@capotchem.com China 18207 66

View Lastest Price from 9-BBN TRIFLATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
9-BBN TRIFLATE pictures 2019-07-10 9-BBN TRIFLATE
62731-43-5
 US $1.00 / KG 1KG 99% 25kg Career Henan Chemical Co
9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE 9-BBN TRIFLATE 9-bbn triflate solution 9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution 9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES 9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E 9-BBN triflate solution, 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in diethyl ether, AcroSeal 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in hexanes, AcroSeal 9-BBN Triflate solution 0.5 M in hexanes 9-BBN·CF3SO3 9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane 9-Borabicyclononyl Trifluoromethanesulfonate 9-Borabicyclo[3.3.1]nonan-9-yl trifluoromethanesulfonate Methanesulfonic acid, 1,1,1-trifluoro-, anhydride with 9-hydroxy-9-borabicyclo[3.3.1]nonane 62731-43-5 C9H14BF3O3S Boranes Synthetic Reagents Reduction