perphthalic acid
- CAS No.
- 2311-91-3
- Chemical Name:
- perphthalic acid
- Synonyms
- perphthalic acid;monoperphthalic acid;Monoperoxyphthalic acid;2-Carboperoxybenzoic acid;Benzenecarboperoxoic acid, 2-carboxy-;2-Carboxy-1-benzeneperoxycarboxylic acid
- CBNumber:
- CB1937576
- Molecular Formula:
- C8H6O5
- Molecular Weight:
- 182.13
- MDL Number:
- MFCD13184286
- MOL File:
- 2311-91-3.mol
- MSDS File:
- SDS
Melting point | 111 °C (decomp)(Solv: ligroine (8032-32-4); ethyl ether (60-29-7)(3:1)) |
---|---|
Boiling point | 407.3±47.0 °C(Predicted) |
Density | 1.507±0.06 g/cm3(Predicted) |
pka | 3.32±0.36(Predicted) |
FDA UNII | Z3STZ5UZ5P |
EPA Substance Registry System | Benzenecarboperoxoic acid, 2-carboxy- (2311-91-3) |
perphthalic acid price
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TRC | M566850 | MonoperoxyphthalicAcid | 2311-91-3 | 1g | $1260 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | CHM0078217 | 2-CARBOPEROXYBENZOIC ACID 95.00% | 2311-91-3 | 10G | $1334.03 | 2021-12-16 | Buy |
Medical Isotopes, Inc. | 60513 | MonoperoxyphthalicAcid | 2311-91-3 | 100mg | $2200 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | CHM0078217 | 2-CARBOPEROXYBENZOIC ACID 95.00% | 2311-91-3 | 5G | $909.56 | 2021-12-16 | Buy |
Labseeker | SC-69883 | 2-CARBONOPEROXOYLBENZOICACID 95 | 2311-91-3 | 5g | $1250 | 2021-12-16 | Buy |
perphthalic acid Chemical Properties,Uses,Production
Uses
Monoperoxyphthalic Acid is used as a reagent in the synthesis of 4-Hydroxyretinoic Acid (H953300); a novel substrate for human liver microsomal UDP-glucuronosyltransferase(s) and recombinant UGT2B7.
Application
Mild peroxycarboxylic acids for effecting epoxidation of π-bonds, Baeyer-Villiger reactions, and the oxidation of diverse heteroatoms including nitrogen, sulfur, and selenium.
Preparation
Monoperoxyphthalic acid is prepared as required by the addition of phthalic anhydride to 30% aqueous Hydrogen Peroxide, in the presence of Sodium Hydroxide or Sodium Carbonate. Magnesium monoperoxyphthalate is prepared by the addition of phthalic anhydride and Magnesium Oxide to aqueous hydrogen peroxide.
Drying: magnesium monoperoxyphthalate should be dried over calcium chloride in a desiccator.
Synthesis Reference(s)
The Journal of Organic Chemistry, 24, p. 1354, 1959 DOI: 10.1021/jo01091a612
storage
Magnesium monoperoxyphthalate may be stored at room temperature. All work should be carried in an efficient fume hood behind a polycarbonate safety screen.
perphthalic acid Preparation Products And Raw materials
Raw materials
Preparation Products
perphthalic acid Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Energy Chemical | 021-58432009 400-005-6266 | marketing1@energy-chemical.com | China | 44807 | 58 |
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd | 029-029-81148696 18161915376 | 1040@dideu.com | China | 9998 | 58 |
Supplier | Advantage |
---|---|
Energy Chemical | 58 |
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd | 58 |