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ChemicalBook >> CAS DataBase List >>perphthalic acid

perphthalic acid

CAS No.
2311-91-3
Chemical Name:
perphthalic acid
Synonyms
perphthalic acid;monoperphthalic acid;Monoperoxyphthalic acid;2-Carboperoxybenzoic acid;Benzenecarboperoxoic acid, 2-carboxy-;2-Carboxy-1-benzeneperoxycarboxylic acid
CBNumber:
CB1937576
Molecular Formula:
C8H6O5
Molecular Weight:
182.13
MDL Number:
MFCD13184286
MOL File:
2311-91-3.mol
MSDS File:
SDS
Last updated:2025-01-16 09:10:03

perphthalic acid Properties

Melting point 111 °C (decomp)(Solv: ligroine (8032-32-4); ethyl ether (60-29-7)(3:1))
Boiling point 407.3±47.0 °C(Predicted)
Density 1.507±0.06 g/cm3(Predicted)
pka 3.32±0.36(Predicted)
FDA UNII Z3STZ5UZ5P
EPA Substance Registry System Benzenecarboperoxoic acid, 2-carboxy- (2311-91-3)

perphthalic acid price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M566850 MonoperoxyphthalicAcid 2311-91-3 1g $1260 2021-12-16 Buy
American Custom Chemicals Corporation CHM0078217 2-CARBOPEROXYBENZOIC ACID 95.00% 2311-91-3 10G $1334.03 2021-12-16 Buy
Medical Isotopes, Inc. 60513 MonoperoxyphthalicAcid 2311-91-3 100mg $2200 2021-12-16 Buy
American Custom Chemicals Corporation CHM0078217 2-CARBOPEROXYBENZOIC ACID 95.00% 2311-91-3 5G $909.56 2021-12-16 Buy
Labseeker SC-69883 2-CARBONOPEROXOYLBENZOICACID 95 2311-91-3 5g $1250 2021-12-16 Buy
Product number Packaging Price Buy
M566850 1g $1260 Buy
CHM0078217 10G $1334.03 Buy
60513 100mg $2200 Buy
CHM0078217 5G $909.56 Buy
SC-69883 5g $1250 Buy

perphthalic acid Chemical Properties,Uses,Production

Uses

Monoperoxyphthalic Acid is used as a reagent in the synthesis of 4-Hydroxyretinoic Acid (H953300); a novel substrate for human liver microsomal UDP-glucuronosyltransferase(s) and recombinant UGT2B7.

Application

Mild peroxycarboxylic acids for effecting epoxidation of π-bonds, Baeyer-Villiger reactions, and the  oxidation of diverse heteroatoms including nitrogen, sulfur, and selenium.

Preparation

Monoperoxyphthalic acid is prepared as required by the addition of phthalic  anhydride to 30% aqueous Hydrogen Peroxide,  in the presence of Sodium Hydroxide or Sodium  Carbonate.  Magnesium monoperoxyphthalate is prepared by the addition of phthalic anhydride and  Magnesium Oxide to aqueous hydrogen peroxide.
Drying: magnesium monoperoxyphthalate should be  dried over calcium chloride in a desiccator.

Synthesis Reference(s)

The Journal of Organic Chemistry, 24, p. 1354, 1959 DOI: 10.1021/jo01091a612

storage

Magnesium monoperoxyphthalate may be stored at room temperature.  All work should be carried in an efficient fume hood behind a polycarbonate safety screen.

perphthalic acid Preparation Products And Raw materials

perphthalic acid Suppliers

Global( 4)Suppliers
Supplier Tel Email Country ProdList Advantage
Energy Chemical 021-58432009 400-005-6266 marketing1@energy-chemical.com China 44807 58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 029-029-81148696 18161915376 1040@dideu.com China 9998 58
perphthalic acid monoperphthalic acid 2-Carboxy-1-benzeneperoxycarboxylic acid Monoperoxyphthalic acid Benzenecarboperoxoic acid, 2-carboxy- 2-Carboperoxybenzoic acid 2311-91-3