Identification | Back Directory | [Name]
perphthalic acid | [CAS]
2311-91-3 | [Synonyms]
perphthalic acid monoperphthalic acid Monoperoxyphthalic acid 2-Carboperoxybenzoic acid Benzenecarboperoxoic acid, 2-carboxy- 2-Carboxy-1-benzeneperoxycarboxylic acid | [EINECS(EC#)]
219-003-5 | [Molecular Formula]
C8H6O5 | [MDL Number]
MFCD13184286 | [MOL File]
2311-91-3.mol | [Molecular Weight]
182.13 |
Hazard Information | Back Directory | [Uses]
Monoperoxyphthalic Acid is used as a reagent in the synthesis of 4-Hydroxyretinoic Acid (H953300); a novel substrate for human liver microsomal UDP-glucuronosyltransferase(s) and recombinant UGT2B7. | [Application]
Mild peroxycarboxylic acids for effecting epoxidation of π-bonds, Baeyer-Villiger reactions, and the oxidation of diverse heteroatoms including nitrogen, sulfur, and selenium. | [Preparation]
Monoperoxyphthalic acid is prepared as required by the addition of phthalic anhydride to 30% aqueous Hydrogen Peroxide, in the presence of Sodium Hydroxide or Sodium Carbonate. Magnesium monoperoxyphthalate is prepared by the addition of phthalic anhydride and Magnesium Oxide to aqueous hydrogen peroxide. Drying: magnesium monoperoxyphthalate should be dried over calcium chloride in a desiccator. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 24, p. 1354, 1959 DOI: 10.1021/jo01091a612 | [storage]
Magnesium monoperoxyphthalate may be stored at room temperature. All work should be carried in an efficient fume hood behind a polycarbonate safety screen. |
|
Company Name: |
Energy Chemical
|
Tel: |
021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
|