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(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one

(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one Struktur
2810-21-1
CAS-Nr.
2810-21-1
Englisch Name:
(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one
Synonyma:
Stepharine;(+)-Stepharine;(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one;(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one;Spiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one, 2',3',8',8'a-tetrahydro-5',6'-dimethoxy-, (8'aR)-
CBNumber:
CB52323100
Summenformel:
C18H19NO3
Molgewicht:
297.34836
MOL-Datei:
2810-21-1.mol

(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one Eigenschaften

Schmelzpunkt:
179-181 °C
Siedepunkt:
487.1±45.0 °C(Predicted)
Dichte
1.27±0.1 g/cm3(Predicted)
storage temp. 
4°C, protect from light
Aggregatzustand
Solid
pka
8.08±0.20(Predicted)
Farbe
Pale purple to purple

Sicherheit

(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A spiroisoquinoline alkaloid from Stephania glabra, the base has [α]26D + 143° (c 1.88, CHCI3). It contains two methoxyl groups and an imino group and yields a crystalline N-acetyl derivative, m.p. 234-5°C; [α]24D- 80° (c 1.57, CHCI3). The N-methyl compound has been shown to be identical with Pronuciferine (q.v.).

Einzelnachweise

Cava et al., Chern. Ind., 282 (1964)
Tomita et al., Tetrahedron Lett., 2825 (1965)
Baldwin et al., J. Chern. Soc., C, 154 (1967)
Circular dichroism: Snatzke, Wollenberg., J. Chern. Soc., C, 1681 (1966)

(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

(8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 15)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Chengdu Greenpure Biopharma CO.,Ltd 		18283602253; +8618283602253
 jancyzheng@gcgreenpure.com China 953 58
TargetMol Chemicals Inc.
support@targetmol.com United States 38630 58
Sichuan Wei Keqi Biological Technology Co., Ltd. 028-81700200 18116577057
 3003855609@qq.com China 7787 56
Beijing Solarbio Science & Tecnology Co., Ltd. 010-50973130 4009686088
 3193328036@qq.com China 29764 68
Chengdu Greenpure Biopharma CO.,Ltd 028-88203606; 18283602253
 jancyzheng@gcgreenpure.com China 1594 58
Shanghai Hongshun Biological Technology Co., Ltd. 15901914505 15901914505
 3187892335@qq.com China 10793 58
BioBioPha Co., Ltd. 0871-65217109
y.liu@mail.biobiopha.com China 1388 58
Shanghai Bohu Biotechnology Co., LTD 021-57763112 13585886131
 3004987436@qq.com China 9693 58
Aleshan (Guangzhou) Biotechnology Co., Ltd 18636736628
 Araratbio@163.com China 3342 58
Shanghai Moqi Biological Technology Co., LTD 021-38218169 13341702378
 190129269@qq.com China 9140 58
  • (+)-Stepharine
  • (8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one
  • (8'aR)-2',3',8',8'a-Tetrahydro-5',6'-dimethoxyspiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopenta[ij]isoquinoline]-4-one
  • Stepharine
  • Spiro[2,5-cyclohexadiene-1,7'(1'H)-cyclopent[ij]isoquinolin]-4-one, 2',3',8',8'a-tetrahydro-5',6'-dimethoxy-, (8'aR)-
  • 2810-21-1
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