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[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat)

PROTOVERATRINE B Struktur
124-97-0
CAS-Nr.
124-97-0
Bezeichnung:
[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat)
Englisch Name:
PROTOVERATRINE B
Synonyma:
yrate);veratetrin;neoprotoveratrin;PROTOVERATRINE B;NEOPROTOVERATRINE;PROTOVERATRINE B (RG);PROTOVERATRINE A (RG)(CALL);4-beta,6-alpha,7-alpha,14,15-alpha-16-beta,20-octol,4,9-epoxy-cevane-3-bet;6,7-diacetate3-(threo-(+)-2,3-dihydroxy-2-methylbutyrate)15-((-)-2-methylbut;4α,9-Epoxycevane-3β,4β,6α,7α,14,15α,16β,20-octol 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate]15-[(R)-2-methylbutanoate]
CBNumber:
CB0376499
Summenformel:
C41H63NO15
Molgewicht:
809.94
MOL-Datei:
124-97-0.mol

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Eigenschaften

Schmelzpunkt:
268-270°C
alpha 
D25 -37° (pyridine); D25 -3.5° (chloroform)
Siedepunkt:
755.18°C (rough estimate)
Dichte
1.1826 (rough estimate)
Brechungsindex
1.6220 (estimate)
storage temp. 
2-8°C
L?slichkeit
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Aggregatzustand
Powder
pka
10.73±0.70(Predicted)

Sicherheit

S-S?tze: 22-24/25
RIDADR  1544
WGK Germany  3
RTECS-Nr. FL5750000
HazardClass  6.1(a)
PackingGroup  II
Toxizit?t LD50 s.c. in male mice: 0.21 mg/kg (Tanaka)

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Also present in Veratrum album, this closely allied alkaloid may be separated from the preceding base by chromatography. It also yields colourless crystals from EtOH and is laevorotatory with [α]29D&o - 39.8° (pyridine) or - 3.5° (CHCI3). In this case, alkaline hydrolysis gives protoverine, two moles of acetic acid, one mole of (-)-2-methylbutyric acid and one mole of 2: 3-dihydroxy-2- methylbutyric acid. It may be distinguished from protoveratrine A by giving a green colour with H2S04. It also forms a complex with maleic acid having m.p. 222.2°C; [α]29D&o - 27.3°.

Einzelnachweise

Stoll, Seebeck., Helv. Chim. Acta., 36,718 (1953)

[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


[3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 19)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387
1057@dideu.com China 3944 58
DAYANG CHEM (HANGZHOU) CO.,LTD
+86-88938639 +86-17705817739
info@dycnchem.com China 53900 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109
market03@meryer.com China 40228 62
821-50328103-801 18930552037
3bsc@sina.com China 15839 69
Shaanxi Dideu Medichem Co. Ltd 029-029-81124267 15229202216
1073@dideu.com China 10006 58
Chengdu Peter-like Biotechnology Co., Ltd. 028-81700200 13308200041
2851167782@qq.com China 11183 58

124-97-0([3β(2R,3R),4α,6α,7α,15α(R),16β]-4,9-Epoxycevan-3,4,6,7,14,15,16,20-octol-6,7-diacetat-3-(2,3-dihydroxy-2-methylbutyrat)-15-(2-methylbutyrat))Verwandte Suche:


  • [3beta(2R,3R),4alpha,6alpha,7alpha,15alpha(R),16beta]-4,9-epoxycevane-3,4,6,7,14,15,16,20-octol 6,7-diacetate 3-(2,3-dihydroxy-2-methylbutyrate) 15-(2-methylbutyrate)
  • PROTOVERATRINE B (RG)
  • PROTOVERATRINE B
  • NEOPROTOVERATRINE
  • 4-beta,6-alpha,7-alpha,14,15-alpha-16-beta,20-octol,4,9-epoxy-cevane-3-bet
  • 4α,9-Epoxycevane-3β,4β,6α,7α,14,15α,16β,20-octol 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate]15-[(R)-2-methylbutanoate]
  • PROTOVERATRINE A (RG)(CALL)
  • 6,7-diacetate3-(threo-(+)-2,3-dihydroxy-2-methylbutyrate)15-((-)-2-methylbut
  • neoprotoveratrin
  • veratetrin
  • yrate)
  • Cevane-3,4,6,7,14,15,16,20-octol, 4,9-epoxy-, 6,7-diacetate 3-[(2R,3R)-2,3-dihydroxy-2-methylbutanoate] 15-[(2R)-2-methylbutanoate], (3β,4α,6α,7α,15α,16β)-
  • 124-97-0
  • C41H63NO15
  • Miscellaneous Natural Products
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