| Identification | More | [Name]
4'-Bromoacetophenone | [CAS]
99-90-1 | [Synonyms]
2,4'-DIBROMOACETOPHENONE
2-BROMO-1-(4-BROMOPHENYL)ETHAN-1-ONE
2-BROMO-1-(4-BROMOPHENYL)ETHANONE
4'-BROMOPHENACYL BROMIDE
4-BROMOPHENACYL BROMIDE
4-Bromophenaeyl bromide
4,OMEGA-DIBROMOACETOPHENONE
AKOS BBS-00000865
ALPHA,4'-DIBROMOACETOPHENONE
ALPHA-4-DIBROMOACETOPHENONE
ALPHA,P-DIBROMOACETOPHENONE
A,P-DIBROMOACETOPHENONE
DIBROMOACETOPHENONE-2,4
GSK-3BETA INHIBITOR VII
OMEGA-BROMOACETOPHENONE
PBPB
P-BROMOPHENACYL BROMIDE
1-(4-bromophenyl)-ethanon
Acetophenone, 4'-bromo-
Ethanone,1-(4-bromophenyl)- | [EINECS(EC#)]
202-783-6 | [Molecular Formula]
C8H7BrO | [MDL Number]
MFCD00000200 | [Molecular Weight]
199.04 | [MOL File]
99-90-1.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystals or | [Melting point ]
108-110 °C(lit.)
| [Boiling point ]
255 °C(lit.)
| [density ]
1.64 | [refractive index ]
1.5540 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
methanol: 0.1 g/mL, clear
| [form ]
Crystals or Crystalline Flakes | [color ]
White to light yellow | [Water Solubility ]
Soluble in Chloroform. Insoluble in water. | [Usage]
Intermediates of Liquid Crystals | [Detection Methods]
GC,NMR | [Merck ]
14,1403 | [BRN ]
386015 | [InChIKey]
WYECURVXVYPVAT-UHFFFAOYSA-N | [CAS DataBase Reference]
99-90-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethanone, 1-(4-bromophenyl)-(99-90-1) | [EPA Substance Registry System]
99-90-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi,Xn | [Risk Statements ]
R34:Causes burns.
R36/38:Irritating to eyes and skin .
R42/43:May cause sensitization by inhalation and skin contact .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S22:Do not breathe dust .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
2
| [RTECS ]
AM6950000
| [F ]
19-21 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29147090 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Bromobenzene-->Aluminium chloride hexahydrate | [Preparation Products]
ETHYL 4-ACETYLBENZOATE-->5-(4-BROMO-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE-->ETHYL 2-AMINO-4-(4-BROMOPHENYL)-3-THIOPHENECARBOXYLATE-->1,3,5-Tris(4-bromophenyl)benzene-->4-(4-BROMOPHENYL)-1,2,3-THIADIAZOLE-->4-Acetylphenylboronic acid-->4-Acetyl-2-fluorobiphenyl-->1-(2-NITRO-BIPHENYL-4-YL)-ETHANONE-->1,3,5-Tris(p-formylphenyl)benzene-->4-Bromophenethyl alcohol-->1,4-Diacetylbenzene-->1-(2-amino[1,1'-biphenyl]-4-yl)ethan-1-one-->2-(4-BROMO-PHENYL)-1H-INDOLE-->2,4'-Dibromoacetophenone-->4-Bromomandelic acid-->1-(4-Bromophenyl)ethylamine hydrochloride-->4-ACETYLBENZALDEHYDE-->4'-BROMO-3-(4-METHYLPHENYL)PROPIOPHENONE |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystals or | [Uses]
Intermediates of Liquid Crystals | [Uses]
Possess activity against positive phototaxis of Chlamydomonas cells.
A fundamental starting material for organic synthesis. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 51, p. 5400, 1986 DOI: 10.1021/jo00376a064
Tetrahedron Letters, 26, p. 4657, 1985 DOI: 10.1016/S0040-4039(00)98778-1 | [Purification Methods]
Crystallise it from EtOH, MeOH or from pet ether (b 80-100o). [Tanner J Org Chem 52 2142 1987, Beilstein 7 IV 647.] |
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