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ChemicalBook--->CAS DataBase List--->82097-50-5

82097-50-5

82097-50-5 Structure

82097-50-5 Structure
IdentificationMore
[Name]

Triasulfuron
[CAS]

82097-50-5
[Synonyms]

1-[2-(2-CHLOROETHOXY)PHENYLSULFONYL]-3-(4-METHOXY-6-METHYL)-(1,3,5-TRIAZIN-2-YL)UREA
2-(2-chloroethoxy)-n-(((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)benzenesulfonamide
AMBER(R)
cga-131036
Herbicide Safener Benoxacor
LOGRAN
LOGRAN(R)
N-(6-methoxy-4-methyl-1,3,5-triazin-2-yl-aminocarbonyl)-2-(2-chloroethoxy)-benzenesulfonamide
TRIASULFURON
1-(2-(2-chloroethoxy)phenylsulfonyl)-3-(4-methoxy-6-methyl-1,3,5-triazin-2-y
2-(2-chloroethoxy)-n-(((4-methoxy-6-methyl-1,3,5-triazin-2-benzenesulfonamid
yl)amino)carbonyl)-
2-(2-chloroethoxy)-N-(((4-methyoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)benzensulfonamide
TRIASULFURON, 100MG, NEAT
TRIASULFURON PESTANAL, 250 MG
TRIASULFURON PESTANAL
triasulfuron (bsi,draft-iso)
TRIASULPHURON
TRISULFURON
triasulfuron 1-[2-(2-chloroethoxy)phenylsulfonyl]-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea
[EINECS(EC#)]

232-520-0
[Molecular Formula]

C14H16ClN5O5S
[MDL Number]

MFCD00145436
[Molecular Weight]

401.83
[MOL File]

82097-50-5.mol
Chemical PropertiesBack Directory
[Melting point ]

178°C
[density ]

1.5218 (rough estimate)
[refractive index ]

1.5630 (estimate)
[storage temp. ]

0-6°C
[form ]

neat
[BRN ]

7151883
[CAS DataBase Reference]

82097-50-5(CAS DataBase Reference)
[EPA Substance Registry System]

82097-50-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN3077 9/PG 3
[WGK Germany ]

2
[RTECS ]

DB1554000
[HS Code ]

29350090
[Hazardous Substances Data]

82097-50-5(Hazardous Substances Data)
[Toxicity]

LD50 in rats (mg/kg): >5000 orally; >2000 dermally; LC50 (4 hr) in rats: >5185 mg/m3 by inhalation (Amrein, Gerber)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-(2-Chloroethoxy)-N-(((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)benzenesulfonamide(82097-50-5).msds
Hazard InformationBack Directory
[Uses]

Herbicide.
[Definition]

ChEBI: An N-sulfonylurea that is N-[o-(2-chloroethoxy)phenyl]sulfonylurea in which one of the hydrogens attached to the non-sulfonylated nitrogen has been replaced by a 4-methoxy-6-methyl-1,3,5-triazin-2-yl group A herbicide used to control broad-leaved weeds in cereals, its use within the EU has been banned after September 2017 on the grounds of potential groundwater contamination and risks to aquatic life.
[Agricultural Uses]

Herbicide: Used for the control of annual ryegrass, paradoxa grass and a wide range of broadleaf weeds in wheat and the post-emergence control of wild radishes in wheat, oats and barley. Registered for use in EU countries . Registered for use in the U.S
[Trade name]

AMBER®; CGA 131036®; LOGRAN®; RAVE®
[Metabolic pathway]

Triasulfuron undergoes hydrolytic degradation, especially under acidic conditions, giving rise to cleavage of the sulfonylurea linkage, producing the major products 2-(2-chloroethoxy)benzenesulfonamide and 4-methyl-6-methoxy-2-amino-1,3,5-triazine and the minor product acetyltriuret. In plants, hydroxylation occurs at the 5-position of the phenyl ring to yield 5- hydroxytriasulfuron as a primary metabolite which is a major metabolite from the plant microsomal system.
By mammals, orally administered triasulfuron is mainly excreted in the urine, and O-dealkylation of 2- chloroethoxy and 6-methoxy groups, and hydroxylation at the 5-position of the phenyl ring and at the 4-methyl group of the triazine ring are observed. By UV irradiation, 2-chloroethoxybenzene is interestingly identified with (4-methoxyl-6-methyl-1,3,5-triazine)urea, and, in sunlight, with these two products, 2-amino-4- methoxyl-6-methyltriazine and 2-(2- chloroethoxy)benzenesulfonamide are identified.
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

82097-50-5(sigmaaldrich)
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