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ChemicalBook--->CAS DataBase List--->5437-45-6

5437-45-6

5437-45-6 Structure

5437-45-6 Structure
IdentificationMore
[Name]

Benzyl 2-bromoacetate
[CAS]

5437-45-6
[Synonyms]

2-BROMO-ACETIC ACID BENZYLESTER
BENZYL 2-BROMOACETATE
BENZYL BROMOACETATE
BROMOACETIC ACID BENZYL ESTER
TIMTEC-BB SBB006752
Acetic acid, bromo-, benzyl ester
Acetic acid, bromo-, phenylmethyl ester
bromo-aceticacibenzylester
bromo-aceticaciphenylmethylester
merbac35
Benzyl-2-Bromoacetate96%
Benzylbromoacetate,97%
Benzyl a-Bromoacetate
bromo-acetic acid phenylmethyl ester
Bromoacetic acid benzyl este
Phenylmethyl 2-bromoacetate
Bromoacetic acid benzyl
[EINECS(EC#)]

226-611-4
[Molecular Formula]

C9H9BrO2
[MDL Number]

MFCD00000190
[Molecular Weight]

229.07
[MOL File]

5437-45-6.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

199-201 °C(Solv: water (7732-18-5))
[Boiling point ]

166-170 °C22 mm Hg(lit.)
[density ]

1.446 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.544(lit.)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Chloroform, Methanol
[form ]

Liquid
[color ]

Clear colorless to light yellow
[Specific Gravity]

1.446
[Water Solubility ]

Not miscible or difficult to mix in water.
[BRN ]

973658
[LogP]

2.368 (est)
[CAS DataBase Reference]

5437-45-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzyl 2-bromoacetate(5437-45-6)
[EPA Substance Registry System]

5437-45-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

2810
[WGK Germany ]

3
[RTECS ]

AF5957215
[F ]

19
[HS Code ]

29159080
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Acemetacin-->Benazepril-->Aceclofenac-->Diethyl (benzyloxycarbonylmethyl)phosphonate, 98 %-->(4-METHYL-PIPERAZIN-1-YL)-ACETIC ACID-->2-Amino-6-chloro-9H-purine-9-acetic acid benzyl ester-->1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetraacetic acid, tris(1,1-diMethylethyl) phenylMethyl ester-->4-Benzyl-morpholin-2-one-->Acemetacin Impurity 4
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Benzyl 2-bromoacetate(5437-45-6).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid.
[Purification Methods]

Dilute the ester with Et2O, wash it with 10% aqueous NaHCO3, H2O, dry (MgSO4) and fractionate it using a Fenske (glass helices packing) column. [Bergmann & Szinai J Chem Soc 1521 1956, Beilstein 6 IV 2265.] LACHRYMATORY.
Spectrum DetailBack Directory
[Spectrum Detail]

Benzyl 2-bromoacetate(5437-45-6)MS
Benzyl 2-bromoacetate(5437-45-6)1HNMR
Benzyl 2-bromoacetate(5437-45-6)13CNMR
Benzyl 2-bromoacetate(5437-45-6)IR1
Benzyl 2-bromoacetate(5437-45-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Benzyl 2-bromoacetate, 96%(5437-45-6)
[Alfa Aesar]

Benzyl bromoacetate, 97%(5437-45-6)
[Sigma Aldrich]

5437-45-6(sigmaaldrich)
[TCI AMERICA]

Benzyl Bromoacetate,>96.0%(GC)(5437-45-6)
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