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ChemicalBook--->CAS DataBase List--->4427-96-7

4427-96-7

4427-96-7 Structure

4427-96-7 Structure
IdentificationMore
[Name]

4-Vinyl-1,3-dioxolan-2-one
[CAS]

4427-96-7
[Synonyms]

4-Ethenyl-1,3-dioxolan-2-one
4-VINYL-1 3-DIOXOLAN-2-ONE 99
Vinyl ethylene carbonate (4-ethenyl-1,3-dioxolan-2-one)
4-VINYL-1,3-DIOXOLAN-2-ONE 99%
4-Vinyl-1,3-dioxolan-2-one
Vinyl Ethylene Carbonate
[EINECS(EC#)]

700-261-7
[Molecular Formula]

C5H6O3
[MDL Number]

MFCD00143315
[Molecular Weight]

114.1
[MOL File]

4427-96-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

237 °C/733 mmHg (lit.)
[density ]

1.188 g/mL at 25 °C(lit.)
[vapor pressure ]

4.58Pa at 25℃
[refractive index ]

n20/D 1.45(lit.)
[Fp ]

206 °F
[storage temp. ]

2-8°C
[form ]

Liquid
[color ]

Colorless to Almost colorless
[Water Solubility ]

Insoluble in water.
[LogP]

-0.24 at 25℃ and pH6.5
[Surface tension]

70.403mN/m at 1g/L and 20℃
[CAS DataBase Reference]

4427-96-7(CAS DataBase Reference)
[EPA Substance Registry System]

4427-96-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R25:Toxic if swallowed.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

1
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29209090
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

It is used to synthesize functional polymers.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 69, p. 2955, 1947 DOI: 10.1021/ja01204a008
[General Description]

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2. The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol. Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

4427-96-7(sigmaaldrich)
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