Identification | More | [Name]
1,1,1-Trifluoro-2,3-epoxypropane | [CAS]
359-41-1 | [Synonyms]
1,1,1-TRIFLUORO-2,3-EPOXYPROPANE 1,2-EPOXY-3,3,3-TRIFLUOROPROPANE 2-(TRIFLUOROMETHYL)OXIRANE 3,3,3-TRIFLUORO-1,2-EPOXYPROPANE 3,3,3-Trifluoro-1,2-epoxypropane~2-(Trifluoromethyl)oxirane 3,3,3-Trifluoro-1,2-epoxypropane, tech 1,2-EPOXY-3,3,3-TRIFLUOROPROPANE, 90+% 1,1,1-Trifluoro-2,3-epoxypropane,tech. 1,2-EPOXY-3,3,3-TRIFLUOROPROPANE: TECH., 85% 1,1,1-TRIFLUORO-2,3-EPOXYPROPANE 98+% 3,3,3-Trifluoropropane epoxide | [EINECS(EC#)]
609-196-8 | [Molecular Formula]
C3H3F3O | [MDL Number]
MFCD00041506 | [Molecular Weight]
112.05 | [MOL File]
359-41-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
F,T | [Risk Statements ]
R11:Highly Flammable. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
1993 | [Hazard Note ]
Flammable/Toxic/Keep Cold | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29109000 |
Hazard Information | Back Directory | [Uses]
1,2-Epoxy-3,3,3-trifluoropropane is used for the synthesis of trifluorolactic acid. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. | [Synthesis]
31g of sodium hydroxide (3.28equiv.: 0.781mol)-water 60ml solution under ice-cooling, 50g bromohydrin form obtained in Example 6 (0.238mol) was added and the internal temperature was raised to 61 oC gas generated was collected outside the reactor, condensed in a trap cooled to -78 oC, 1,1,1-trifluoro-2 ,3-epoxypropane was obtained in 84% yield. This was analyzed by 1H-NMR, 19F-NMR. 19F-NMR: (acetone weight):-86.90ppm (3F, d) 1H-NMR: (acetone weight): 2.90ppm (1H, m) 2.96ppm (1H, d d), 3.40ppm (1H, m)
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