| Identification | More | [Name]
[Bis(trifluoroacetoxy)iodo]benzene | [CAS]
2712-78-9 | [Synonyms]
BIS(TRIFLUORACETOXY)-IODOBENZENE
[BIS(TRIFLUOROACETOXY)IODO]BENZENE
BTI
DFAIB
IODINE, PHENYLBIS(TRIFLUOROACETATO)-
IODOBENZENE BIS(TRIFLUOROACETATE)
IODOBENZENE I,I-BIS(TRIFLUOROACETATE)
IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE)
LABOTEST-BB LT00454809
PIFA
BTI~Iodosobenzene bis(trifluoroacetate)~Phenyliodine(III) bis(trifluoroacetate)~PIFA
phenylbis(trifluoroacetato-O)iodine
Bis-Trifluoroacetoxyiodobenzene99%
Bis-Trifluoroacetoxyiodobenzene 99%
Iodosobenzene-bis(trifluoroacetate)
Phenyliodine(III)bis(trifluoroacetate)
Iodine, phenylbis(trifluoroacetato-.kappa.O)-
bis(I,I-trifluoroacetoxy)iodobenzene
Bis(trifluoroacetoxy)iodoübenzene, 97%
BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA | [EINECS(EC#)]
220-308-0 | [Molecular Formula]
C10H5F6IO4 | [MDL Number]
MFCD00009672 | [Molecular Weight]
430.04 | [MOL File]
2712-78-9.mol |
| Chemical Properties | Back Directory | [Appearance]
White to pale yellow crystalline powder | [Melting point ]
121-125 °C(lit.)
| [storage temp. ]
Keep Cold | [solubility ]
Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly) | [form ]
Crystalline Powder | [color ]
White to pale yellow | [Water Solubility ]
insoluble | [Sensitive ]
Moisture & Light Sensitive | [BRN ]
764767 | [Stability:]
Air and Moisture Sensitive | [CAS DataBase Reference]
2712-78-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
4.10-8-9-21 | [Hazard Note ]
Irritant/Keep Cold | [HazardClass ]
IRRITANT, KEEP COLD, LIGHT SENSITIVE | [HS Code ]
29039990 |
| Hazard Information | Back Directory | [Chemical Properties]
White to pale yellow crystalline powder | [Uses]
In oxidation, cyclization, dehydrogenation, and dearomatization reactions. | [reaction suitability]
reagent type: oxidant | [Purification Methods]
Crystallise the iodo compound from warm trifluoroacetic acid and dry it over NaOH pellets. Recrystallise it also from Me2CO/pet ether. Its melting point depends on the heating rate. [Spyroudis & Varvoglis Synthesis 445 1975, application: Almond et al. Org Synth 66 132 1988.] |
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