Identification | More | [Name]
(S)-(+)-alpha-Methoxyphenylacetic acid | [CAS]
26164-26-1 | [Synonyms]
O-METHYL-L-MANDELIC ACID (S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID (S)-ALPHA-METHOXYPHENYLACETIC ACID (S)-(+)-A-METHOXYPHENYLACETIC ACID (S)-(+)-METHOXYPHENYLACETIC ACID Methoxy(phenyl)acetic acid (S)-(+)-A-METHOXYPHENYLACETIC ACID FLU& O-Methyl-(S)-mandelicacid (s)-(+)-à-methoxyphenylacetic acid (S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID 99% (S)-(+)-ɑ-Methoxyphenylacetic acid, 99% (2S)-2-Methoxy-2-phenylacetic acid (S)-α-Methoxybenzeneacetic acid (αS)-α-Methoxybenzeneacetic acid [S,(+)]-α-Methoxybenzeneacetic acid | [EINECS(EC#)]
247-492-5 | [Molecular Formula]
C9H10O3 | [MDL Number]
MFCD00064216 | [Molecular Weight]
166.17 | [MOL File]
26164-26-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29189900 |
Hazard Information | Back Directory | [Chemical Properties]
White Solid | [Uses]
(S)-(+)-α-Methoxyphenylacetic Acid (cas# 26164-26-1) is a compound useful in organic synthesis. | [Uses]
Reactant involved in the synthesis of biologically active molecules including:
- Acyclonucleoside phosphonates structural analogs of adefovir
- Labeled discodermolide for studying binding to tubulin
- 10-Isocyano-4-cadinene used for antifouling activity
Reactant involved in studies of immunostimulating chromanones gonytolides A-C
Reactant involved in:
- Hydroxylations and epoxidations
- Hydrogenations
| [Purification Methods]
Purify the acids by recrystallising from *C6H6/pet ether (b 80-100o). [Neilson & Peters J Chem Soc 1519 1962, Weizmann et al. J Am Chem Soc 70 1153 1948, Pirie & Smith J Chem Soc 338 1932, NMR: Dale & Mosher J Am Chem Soc 9 5 512 1973, for resolution: Roy & Deslongchamps Can J Chem 63 651 1985, Trost et al. J Am Chem Soc 1 0 8 4974 1986.] The racemic mixture has m 72o, b 121-122o/0.4mm, 165o/18mm (from pet ether) [Braun et al. Chem Ber 6 3 2847 1930]. [Beilstein 10 IV 566.] |
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