| Identification | More | [Name]
alpha-Toluenesulfonyl chloride | [CAS]
1939-99-7 | [Synonyms]
ALPHA-TOLUENESULFONYL CHLORIDE
ALPHA-TOLUENESULPHONYL CHLORIDE
ALPHA-TOLYLSULFONYL CHLORIDE
A-TOLUENESULFONYL CHLORIDE
BENZYLSULFONYL CHLORIDE
BENZYLSULPHONYL CHLORIDE
OTAVA-BB BB7020430779
PHENYLMETHANESULFONYL CHLORIDE
PHENYLMETHYLSULFONYLCHLORIDE
PMS-CL
Benzenemethanesulfonylchloride
Benzylsulfochloride
Methanesulfonyl chloride, phenyl-
Phenylmethane sulfo chloride
alpha-Benzylsulphonyl chloride~Phenylmethanesulphonyl chloride~Phenylmethylsulphonyl chloride
toluene-alpha-sulphonyl chloride
Phenylmethanesulfonylchloride4-4ethylthioanisole
à-benzylsulfonyl chloride
à-toluenesulfonyl chloride
Toluene a-sulfonyl chloride. | [EINECS(EC#)]
217-717-1 | [Molecular Formula]
C7H7ClO2S | [MDL Number]
MFCD00007455 | [Molecular Weight]
190.65 | [MOL File]
1939-99-7.mol |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Corrosive | [TSCA ]
T | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29049020 |
| Hazard Information | Back Directory | [Chemical Properties]
almost white crystalline powder | [Uses]
a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013
Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333 | [General Description]
Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied. |
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