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ChemicalBook--->CAS DataBase List--->18291-80-0

18291-80-0

18291-80-0 Structure

18291-80-0 Structure
IdentificationMore
[Name]

TRIMETHYLSILYL BROMOACETATE
[CAS]

18291-80-0
[Synonyms]

BROMOACETIC ACID TRIMETHYLSILYL ESTER
TRIMETHYLSILYL BROMOACETATE
Acetic acid, bromo-, trimethylsilyl ester
Trimethylsilyl bromoacetate, 98+%
2-Bromoacetic acid trimethylsilyl ester
[EINECS(EC#)]

242-165-3
[Molecular Formula]

C5H11BrO2Si
[MDL Number]

MFCD00000187
[Molecular Weight]

211.13
[MOL File]

18291-80-0.mol
Chemical PropertiesBack Directory
[Appearance]

Clear slightly yellow liquid
[Boiling point ]

57-58 °C/9 mmHg (lit.)
[density ]

1.284 g/mL at 25 °C(lit.)
[vapor density ]

>1 (vs air)
[refractive index ]

n20/D 1.442(lit.)
[Fp ]

83 °F
[storage temp. ]

Flammables area
[Specific Gravity]

1.299
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

1927560
[CAS DataBase Reference]

18291-80-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R10:Flammable.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2920 8/PG 2
[WGK Germany ]

3
[F ]

10-19-21
[TSCA ]

No
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29310099
Hazard InformationBack Directory
[Chemical Properties]

Clear slightly yellow liquid
[Uses]

Trimethylsilyl bromoacetate has been used:
  • in the preparation of new imidazolium salts functionalized with the trimethylsilyl ester group
  • as alkylating agent in the synthesis of succinate fragment of pantocin B (antibiotic natural product)
  • in the synthesis of taxol derivatives tethered at C2′ and C-7 to glutamate and folate
Spectrum DetailBack Directory
[Spectrum Detail]

TRIMETHYLSILYL BROMOACETATE(18291-80-0)MS
TRIMETHYLSILYL BROMOACETATE(18291-80-0)1HNMR
TRIMETHYLSILYL BROMOACETATE(18291-80-0)13CNMR
TRIMETHYLSILYL BROMOACETATE(18291-80-0)IR1
TRIMETHYLSILYL BROMOACETATE(18291-80-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Trimethylsilyl bromoacetate, 98%(18291-80-0)
[Alfa Aesar]

Trimethylsilyl bromoacetate, 98+%(18291-80-0)
[Sigma Aldrich]

18291-80-0(sigmaaldrich)
[TCI AMERICA]

Bromoacetic Acid Trimethylsilyl Ester,>96.0%(GC)(18291-80-0)
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