Identification | More | [Name]
(-)-MENTHYL CHLOROFORMATE | [CAS]
14602-86-9 | [Synonyms]
(1R,2S,5R)-(-)-MENTHYLCHLOROFORMATE (-)-(1R)-MENTHYL CHLOROFORMATE (1R)-(-)-MENTHYL CHLOROFORMATE (-)-CHLOROFORMYLOXY-P-MENTHANE MCF (-)-MENTHYL CHLOROFORMATE Chloroformic acid (1R)-menthyl ester~L-Menthyl chloroformate L-p-menth-3-yl chloroformate (-)-(1R)-Menthyl chloroformate (99% EE/GLC) (1R)-(-)-MENTHYL CHLOROFORMATE 95+% L-MenthylChloroformate (1R)-Menthylester Chloroformicacid Carbonochloridic acid, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester chloroformic acid (1r)-menthyl ester (-)-Menthyloxycarbonyl chloride (S)-Menthyl chloroformate Chloroformic acid (1R,3R,4S)-p-menthane-3-yl ester Chloroformic acid [[1R,2S,5R,(-)]-2-isopropyl-5-methylcyclohexyl] ester (-)-Chloroformic acid 2-(1-methylethyl)-5-methylcyclohexyl ester | [EINECS(EC#)]
672-624-7 | [Molecular Formula]
C11H19ClO2 | [MDL Number]
MFCD00009694 | [Molecular Weight]
218.72 | [MOL File]
14602-86-9.mol |
Chemical Properties | Back Directory | [Boiling point ]
108-109 °C11 mm Hg(lit.) | [density ]
1.031 g/mL at 20 °C(lit.)
| [vapor pressure ]
0.01 psi ( 20 °C)
| [refractive index ]
n20/D 1.459
| [Fp ]
158 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Sparingly), Methanol (Sparingly) | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [optical activity]
[α]20/D 83°, c = 1 in chloroform | [Sensitive ]
Moisture Sensitive | [BRN ]
2414686 | [CAS DataBase Reference]
14602-86-9(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R23:Toxic by inhalation. R34:Causes burns. R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3277 6.1/PG 2
| [WGK Germany ]
3
| [F ]
10-19-21 | [HS Code ]
2915.90.5010 | [HazardClass ]
6.1 | [PackingGroup ]
II |
Hazard Information | Back Directory | [Uses]
Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields. |
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