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ChemicalBook--->CAS DataBase List--->123-90-0

123-90-0

123-90-0 Structure

123-90-0 Structure
IdentificationMore
[Name]

Thiomorpholine
[CAS]

123-90-0
[Synonyms]

4-THIOMORPHOLINE
TETRAHYDRO-1,4-THIAZINE
TETRAHYDRO-2H-1,4-THIAZINE
TETRAHYDRO-4H-1,4-THIAZINE
THIAMORPHOLINE
THIOMORPHOLINE
1,4-Thiazan
1,4-Thiazane
1,4-Thiazine, tetrahydro-
1-Thia-4-azacyclohexane
Parathiazan
thiazinane
thiazolidinane
Tetrahydro-2H-1,4-thiazine, Thiamorpholine
[EINECS(EC#)]

204-660-2
[Molecular Formula]

C4H9NS
[MDL Number]

MFCD00005974
[Molecular Weight]

103.19
[MOL File]

123-90-0.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless to yellow liquid
[Melting point ]

166-168
[Boiling point ]

169 °C (lit.)
[density ]

1.026 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.538(lit.)
[Fp ]

140 °F
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[solubility ]

organic solvents: miscible(lit.)
[form ]

clear liquid
[pka]

9.14±0.20(Predicted)
[color ]

Colorless to Light yellow to Light orange
[Water Solubility ]

Miscible with waterMiscible with water and organic solvents.
[Sensitive ]

Air Sensitive
[Merck ]

14,9300
[BRN ]

102550
[InChIKey]

BRNULMACUQOKMR-UHFFFAOYSA-N
[Uses]

Organic synthesis.
[CAS DataBase Reference]

123-90-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Thiomorpholine(123-90-0)
[Storage Precautions]

Air sensitive
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R37:Irritating to the respiratory system.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3267 8/PG 3
[WGK Germany ]

3
[F ]

10-13-23
[Hazard Note ]

Irritant
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29349990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Ethyl acetate-->Methanol-->Dichloromethane-->Potassium carbonate-->Sodium bicarbonate-->Sodium sulfide nonahydrate-->Bis(2-chloroethyl)amine hydrochloride
[Preparation Products]

N-Morpholinothio Phthaldamide-->Thiomorpholine-1,1-dioxide-->4-(thiomorpholin-4-yl)benzonitrile-->4-(4-BROMOBENZYL)THIOMORPHOLINE-->N-(2-HYDROXYPROPYL) THIOMORPHOLINE-->4-Methylthiomorpholine-->4-(4-Bromophenyl)Thiomorpholine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Thiomorpholine(123-90-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to yellow liquid
[Definition]

ChEBI: A saturated organic heteromonocyclic parent that is an analogue of morpholine where the oxygen atom is replaced by sulfur.
[General Description]

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.
[Purification Methods]

Purify it by vacuum distillation. The hydrochloride has m 179o (from isoPrOH or EtOH/Et2O/HCl). [Davies J Chem Soc 306 1920, Beilstein 27 II 4, 2 III/IV 636.]
Spectrum DetailBack Directory
[Spectrum Detail]

Thiomorpholine(123-90-0)MS
Thiomorpholine(123-90-0)1HNMR
Thiomorpholine(123-90-0)13CNMR
Thiomorpholine(123-90-0)IR1
Thiomorpholine(123-90-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Thiomorpholine, 97%(123-90-0)
[Alfa Aesar]

Thiomorpholine, 98%(123-90-0)
[Sigma Aldrich]

123-90-0(sigmaaldrich)
[TCI AMERICA]

Thiomorpholine,>97.0%(GC)(123-90-0)
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