| Identification | More | [Name]
Decabromodiphenyl oxide | [CAS]
1163-19-5 | [Synonyms]
1,1'-Oxybis(2,3,4,5,6-pentabromobenzene)
BDE-209
BDE NO 209
BIS(PENTABROMOPHENYL) ETHER
DECA
DECABROMODIPHENYL ETHER
DECABROMODIPHENYL OXIDE
PENTABROMOPHENYL ETHER
PERBROMODIPHENYL ETHER
SAYTEX 102E
SAYTEX(R) 102E FLAME RETARDANT
1,1’-oxybis(2,3,4,5,6-pentabromo-benzen
1,1’-oxybis[2,3,4,5,6-pentabromo-benzen
berkflamb10e
br55n
bromkal82-0de
bromkal82-ode
bromkal83-10de
dbdpo
de83r | [EINECS(EC#)]
214-604-9 | [Molecular Formula]
C12Br10O | [MDL Number]
MFCD00000059 | [Molecular Weight]
959.17 | [MOL File]
1163-19-5.mol |
| Chemical Properties | Back Directory | [Appearance]
DBDPO is a white to off-white powder.
A polybrominated biphenyl. | [Melting point ]
>300 °C(lit.) | [Boiling point ]
425°C | [density ]
3 g/cm3 | [vapor pressure ]
0Pa at 21℃ | [refractive index ]
1.5000 (estimate) | [Fp ]
-12 °C | [storage temp. ]
2-8°C | [solubility ]
<0.0001mg/l | [form ]
Solid | [color ]
White to Light Brown | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
<0.1 g/100 mL at 20 ºC | [BRN ]
2188438 | [InChIKey]
WHHGLZMJPXIBIX-UHFFFAOYSA-N | [LogP]
6.625 at 25℃ | [CAS DataBase Reference]
1163-19-5(CAS DataBase Reference) | [IARC]
3 (Vol. 48, 71) 1999 | [EPA Substance Registry System]
1163-19-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi,N,F | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste . | [RIDADR ]
3152 | [WGK Germany ]
1
| [RTECS ]
KN3525000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HazardClass ]
9 | [PackingGroup ]
II | [HS Code ]
29093031 | [Safety Profile]
Questionable carcinogen with experimental neoplastigenic data. Experimental reproductive effects. Used as a flame retardant for thermoplastics. When heated to decomposition it emits toxic fumes of Br-. See also ETHERS and BROMIDES | [Hazardous Substances Data]
1163-19-5(Hazardous Substances Data) | [Toxicity]
Review IARC: Group 3 IMEMDT 48,73,90; Animal Limited Evidence IMEMDT 48,73,90. NTP Carcinogenesis Studies (feed); Some Evidence: rat NTPTR* NTP-TR-309,86; (feed); Equivocal Evidence: mouse NTPTR* NTP-TR-309,86. Polybrominated biphenyl compounds ar |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Government regulation-->Diphenyl ether-->Aluminum-->Dichloroethane-->CHLOROETHANE-->Dibromomethane-->Poly(butylene terephthalate)-->1,1,2,2-Tetrachloroethane-->CHLOROPICRIN & ETHYLENE DIBROMIDE-->Bromate/Bromide, 0.1N Standardized Solution | [Preparation Products]
Poly(butylene terephthalate)-->2,2',3,3',4,4',5,5',6-nonabromodiphenylether-->2,2,3,3,4,5,5,6,6-NONABROMODIPHENYL ETHER |
| Hazard Information | Back Directory | [Description]
DBDPO is a white to off-white powder.Molecular weight = 959.9. Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability 0,Reactivity 0. Slightly soluble in water. | [Chemical Properties]
Decabromodiphenyl Oxide (DBDPO) is a white to off-white or light yellow powder. Almost insoluble in all solvents. Good thermal stability. Heated to 354 ℃, weight loss 5%. It is a non-toxic and non-polluting flame retardant. | [Uses]
Decabromodiphenyl ether is a brominated flame retardant that is used in conjunction with antimony trioxide in high impact polystyrene. DecaBDE is used as an additive flame retardant, and has a variety of applications including in plastics/polymers/composites, textiles, adhesives, sealants, coatings and inks. DecaBDE containing plastics are used in housings of computers and TVs, wires and cables, pipes and carpets. Adverse effects are reported for soil organisms, birds, fish, frog, rat, mice and humans. One of the new POPs under the Stockholm Convention | [Application]
Decabromodiphenyl oxide is an unreactive, additive flame retardant widely used for its thermal stability and its low cost in thermoplastic resins, thermoset resins, textiles and adhesives. The major applications are in high impact polystyrene, glass reinforced thermoplastic polyester and moulding resins, low density polyethylene extrusion coatings, polypropylene (homo- and copolymers), acrylonitrile butadiene styrene rubber, nylon and polyvinyl chloride. | [Definition]
ChEBI: Decabromodiphenyl ether is a polybromodiphenyl ether that is diphenyl ether in which all of the hydrogens have been replaced by bromines. It has a role as a neurotoxin. | [Preparation]
Decabromodiphenyl ether can be synthesized by reacting diphenyl ether with bromine in the presence of halogenated catalyst (iron powder, etc.).
The diphenyl ether is dissolved in the solvent, the catalyst is added, and then bromine is added to carry out the reaction. After the reaction, filter, wash and dry to obtain decabromodiphenyl ether. Commonly used solvents are dibromoethane, dichloroethane, dibromomethane, carbon tetrachloride, tetrachloroethane and the like. | [General Description]
White to off-white powder with a chemical odor. | [Air & Water Reactions]
Insoluble in water. | [Reactivity Profile]
Decabromodiphenyl oxide(1163-19-5) is incompatible with strong oxidizers . | [Fire Hazard]
Flash point data for Decabromodiphenyl oxide are not available; however, Decabromodiphenyl oxide is probably combustible. | [Potential Exposure]
It is used as a fire retardant for
thermoplastics and man-made fibers. | [First aid]
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit. | [storage]
Color Code—Green: General storage may be used.Prior to working with DPDPO you should be trained on itsproper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers.Where possible, automatically transfer this chemical fromdrums or other storage containers to process containers. Useonly nonsparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition, such as smoking and open flames, are prohibited wherethis chemical is used, handled, or stored in a manner thatcould create a potential fire or explosion hazard. Whereverthis chemical is used, handled, manufactured, or stored, useexplosion-proof electrical equipment and fittings. | [Shipping]
UN3077 Environmentally hazardous substances,
solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous
hazardous material, Technical Name Required. UN3152
Polyhalogenated biphenyls, solid or Polyhalogenated ter-
phenyls, solid, Hazard class: 9; Labels: 9-Miscellaneous
hazardous material. | [Incompatibilities]
Incompatible with strong oxidizers (chlo-
rates, nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.); contact may cause fires
or explosions. Keep away from alkaline materials, strong
bases, strong acids, oxoacids, and epoxides. Ethers have
a tendency to form unstable and explosive peroxides. | [Toxics Screening Level]
The Initial Threshold Screening Level (ITSL) for decabromodiphenyl ether (DBDPE) is
25 μg/m3 with 24-hr averaging time. The Initial Risk Screening Level (IRSL) for
DBDPE is 5 μg/m3 and the Secondary Risk Screening Level (SRSL) is 50 μg/m3; both
with annual averaging time. |
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