| Identification | More | [Name]
CIS-1,3-DICHLOROPROPENE | [CAS]
10061-01-5 | [Synonyms]
CIS-1,3-DICHLORO-1-PROPENE
CIS-1,3-DICHLOROPROPENE
CIS-3-CHLOROALLYL CHLORIDE
(1Z)-1,3-Dichloro-1-propene
(z)-1,3-dichloro-1-propene
(Z)-1,3-Dichloropropene
3-dichloro-(z)-1-propen
3-dichloro-(z)-propen
cis-1,3-dichloropropenesingle*componentstandard
cis-1,3-Dichloropropylene
cis-dcp
Propene, 1,3-dichloro-, (Z)-
cis-1,3-Dichloropropene (1mg/ml in methanol)
1 3-DICHLOROPROPENE (ISOMERIC) 2000MG &
1,3-DICHLOROPROPENE,(ISOMERIC), 2000MG, NEAT
CIS-1 3-DICHLOROPROPENE NEAT STANDARD &
CIS-1,3-DICHLOROPROPENE, 100MG, NEAT
cis-1,3-dichloropropene (technical)
1,3-CIS-DICHLOROPROPENE
1,3-DICHLOROPROPENE(CIS) | [EINECS(EC#)]
233-195-8 | [Molecular Formula]
C3H4Cl2 | [MDL Number]
MFCD00062949 | [Molecular Weight]
110.97 | [MOL File]
10061-01-5.mol |
| Chemical Properties | Back Directory | [Appearance]
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor. | [Melting point ]
-50 °C | [Boiling point ]
104 °C(lit.) | [density ]
1.225 g/mL at 25 °C(lit.)
| [vapor pressure ]
111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002) | [refractive index ]
n20/D 1.4675(lit.)
| [Fp ]
75 °F
| [storage temp. ]
0-6°C
| [Stability:]
Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive. | [Water Solubility ]
1.071g/L(30 ºC) | [Merck ]
3075 | [Henry's Law Constant]
1.23 x 10-3 atm?m3/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003) | [Exposure limits]
ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted). | [CAS DataBase Reference]
10061-01-5(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Propene, 1,3-dichloro-, (Z)-(10061-01-5) | [EPA Substance Registry System]
10061-01-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N,F | [Risk Statements ]
R10:Flammable.
R20/21:Harmful by inhalation and in contact with skin .
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S16:Keep away from sources of ignition-No smoking .
S7:Keep container tightly closed . | [RIDADR ]
UN 2047 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
UC8325000
| [HazardClass ]
3.2 | [PackingGroup ]
III | [Safety Profile]
Confirmed carcinogen
with experimental neoplastigenic data.
Human mutation data reported. A
dangerous fire hazard when exposed to heat,
flame, or oxidzers. When heated to
decomposition it emits toxic fumes of Cl-.
See also CHLORINATED
HYDROCARBONS , ALIPHATIC . | [Hazardous Substances Data]
10061-01-5(Hazardous Substances Data) | [Toxicity]
LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing
and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats
is 713 and 470 mg/kg, respectively (Verschueren, 1983). |
| Hazard Information | Back Directory | [General Description]
Colorless to amber liquid with a sweetish odor. | [Reactivity Profile]
CIS-1,3-DICHLORO-1-PROPENE(10061-01-5) may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Potential Exposure]
Used as a soil fumigant prior to
planting crops, such as cotton, sugar beet, potatoes; used in
combinations with dichloropropanes as a soil fumigant.
Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide. | [Fire Hazard]
Flash point data for this chemical are not available, however literature sources indicate that this material is flammable. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids.
Seek medical attention immediately. If this chemical
contacts the skin, remove contaminated clothing and wash
immediately with soap and water. Seek medical attention
immediately. If this chemical has been inhaled, remove
from exposure, begin rescue breathing (using universal
precautions, including resuscitation mask) if breathing has
stopped and CPR if heart action has stopped. Transfer
promptly to a medical facility. When this chemical
has been swallowed, get medical attention. Give large
quantities of water and induce vomiting. Do not make an
unconscious person vomit. | [Shipping]
UN2047 Dichloropropene, Hazard Class: 3;
Labels: 3-Flammable liquid. | [Incompatibilities]
Vapor may form explosive mixture
with air. Incompatible with oxidizers (chlorates, nitrates,
peroxides, permanganates, perchlorates, chlorine, bromine,
fluorine, etc.); contact may cause fires or explosions. Keep
away from alkaline materials, strong bases, strong acids,
oxoacids, and epoxides. May accumulate static electrical
charges, and may cause ignition of its vapors. Incompatible
with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials;
halogens, or corrosives. Note: Epichlorohydrin may be
added as a stabilizer. | [Chemical Properties]
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor. | [Chemical Properties]
colourless to amber liquid | [Waste Disposal]
Incineration, preferably
after mixing with another combustible fuel. Care must be
exercised to assure complete combustion to prevent the
formation of phosgene. An acid scrubber is necessary to
remove the halo acids produced. In accordance with
40CFR165, follow recommendations for the disposal of
pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting
your local or federal environmental control agency, or by
contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment, and waste disposal. | [Physical properties]
Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor.
Evaporates quickly when spilled. The average least detectable odor threshold concentration in
water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al.,
1982). | [Uses]
The isomeric mixture is used as a soil fumigant and a nematocide. | [Definition]
ChEBI: The (Z)-isomer of 1,3-dichloropropene. | [Environmental Fate]
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen-
1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized
to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors
et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation
in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted
at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to
volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser,
1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol
and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993).
Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation
of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl
chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon
et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C
using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6
minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic
phosgene (Sittig, 1985). | [Solubility in organics]
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene,
and trichloroethylene. | [Solubility in water]
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene,
and trichloroethylene. |
|
|