ChemicalBook CAS DataBase List TRIPHENYLTIN HYDRIDE

TRIPHENYLTIN HYDRIDE synthesis

10synthesis methods

Product Name:TRIPHENYLTIN HYDRIDE
CAS Number:892-20-6
Molecular formula:C18H16Sn
Molecular Weight:351.03

The Preparative Method of Triphenylstannane: reduction of Chlorotriphenylstannane with Lithium Aluminum Hydride in ether or with Sodium Borohydride in glyme; reduction of bis(triphenyltin) oxide with polymethylhydrosiloxane; reduction of triphenyltin methoxide with diborane; protonation of Ph3SnLi. The reagent was also generated in situ from Ph3SnCl and Sodium Cyanoborohydride in t-butyl alcohol.

58-22-0 Synthesis

58-22-0
410 suppliers
$19.00/1 mg

639-58-7 Synthesis

639-58-7
190 suppliers
$20.00/10 g

892-20-6
49 suppliers
$75.59/5g

Yield:-

Reaction Conditions:

in ethanol

Steps:

3 TRIPHENYLTIN TESTOSTERONYL ETHER
EXAMPLE 3 TRIPHENYLTIN TESTOSTERONYL ETHER 3.5 g of triphenyltin chloride was dissolved in 40 ml of ethanol and 2.8 g of testosterone was dissolved in 40 ml of ethanol. Both solutions were mixed in a 200 ml round bottom flask fitted with a soxhlet and a reflux condenser. The mixture was refluxed for 3 hours at 78°-80° C. The reaction product duct was filtered and evaporated to 1/4 its volume, then cooled to form a powder. Appearance: amorphous powder Melting point: 75°-80° C. MW (determined by mass spec): 720

References:

Cardarelli;Nathan F.;Kanakkanatt;Sebastian V. US4634693, 1987, A

16853-85-3 Synthesis