TETRABROMO-THIENO[3,2-B]THIOPHENE synthesis
- Product Name:TETRABROMO-THIENO[3,2-B]THIOPHENE
- CAS Number:124638-53-5
- Molecular formula:C6Br4S2
- Molecular Weight:455.81
![Thieno[3,2-b]thiophene](/CAS/GIF/251-41-2.gif)
251-41-2
273 suppliers
$8.00/250mg
124638-53-5
71 suppliers
$65.00/50mg
Yield: 95%
Reaction Conditions:
with bromine;acetic acid in chloroform at 20 - 78;
Steps:
1.1
S1,willAnd thiophenethienothiophene(5 g, 35.7 mmol)Soluble in glacial acetic acid (36ml)And chloroform (10 ml)Of the mixed solvent,Br2 is added dropwise at room temperature(28.5 g, 180.56 mmol),Continue to stir for half an hour,And then heated to reflux at room temperature of 78 ° C overnight; Ling to room temperature, washed with water, precipitation of white solid compounds, and then washed with water and methanol 3 times, vacuum drying at room temperature,To give white solid compound 1, [M +] = 455.0 (yield: 95%);
References:
Beijing University Shenzhen Sheng Yuan;Meng Hong;Shi Jingjing CN106188090, 2016, A Location in patent:Paragraph 0086
![THIENO[3,2-B]THIOPHENE-2-CARBOXYLIC ACID](/CAS/GIF/1723-27-9.gif)
1723-27-9
128 suppliers
$21.00/100mg
124638-53-5
71 suppliers
$65.00/50mg
![2,3,5-tribromothieno[3,2-b]thiophene](/CAS2/GIF/25121-88-4.gif)
25121-88-4
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$501.91/5MG
124638-53-5
71 suppliers
$65.00/50mg
930-96-1
241 suppliers
$11.00/1g
124638-53-5
71 suppliers
$65.00/50mg
![Thieno[3,2-b]thiophene-2-carboxylic acid ethyl ester](/CAS2/GIF/201004-08-2.gif)
201004-08-2
39 suppliers
$77.76/250mgs:
124638-53-5
71 suppliers
$65.00/50mg