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ChemicalBook CAS DataBase List (S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
340-06-7

(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL synthesis

8synthesis methods
-

Yield: 100%

Reaction Conditions:

with (S,S)-RuCl2(2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl)(1,1-dianisyl-2-isopropyl-1,2-ethylenediamine);potassium tert-butylate;hydrogen in isopropyl alcohol at 26 - 30; under 7600 Torr; for 16 h;

References:

Ohkuma;Koizumi;Doucet;Pham;Kozawa;Murata;Katayama;Yokozawa;Ikariya;Noyori [Journal of the American Chemical Society,1998,vol. 120,# 51,p. 13529 - 13530]

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