Methyl trichloroacetate synthesis
- Product Name:Methyl trichloroacetate
- CAS Number:598-99-2
- Molecular formula:C3H3Cl3O2
- Molecular Weight:177.41
76-02-8
254 suppliers
$59.70/50g
598-99-2
162 suppliers
$21.21/10gm:
23170-77-6
10 suppliers
inquiry
Yield:-
Reaction Conditions:
in methanol
Steps:
5.J EXAMPLE 5J
Methyl trichloroacetate formed cleanly and completely from the reaction of trichloroacetyl chloride with methanol. 13C NMR (CD3CN): δ 162.55, 89.75, 56.14 (OH3). GC-MS showed a single peak in the TIC: m/z 141 (M+-Cl). N-Methyl trichloroacetamide formed cleanly and completely from the reaction of trichloroacetyl chloride with aqueous 40% methylamine. 13C NMR (CD3CN): δ 162.50, 92.74, 27.41 (NH3). GC-MS showed a single peak in the TIC: mlz 175 (M+). Calculated C3H8Cl3N2O (M+NH4+) exact masses for chlorine isotopes=192.9697, 194.9667, 196.9638. Found 192.9732, 194.9711, 196.9643.
References:
Pharmacia Corporation US2003/80320, 2003, A1
77-78-1
313 suppliers
$19.69/1ml
76-03-9
431 suppliers
$14.00/25g
598-99-2
162 suppliers
$21.21/10gm:
116-54-1
206 suppliers
$5.00/5 g
421-83-0
246 suppliers
$22.39/1G
598-99-2
162 suppliers
$21.21/10gm:
67-56-1
771 suppliers
$7.29/5ml-f
76-03-9
431 suppliers
$14.00/25g
598-99-2
162 suppliers
$21.21/10gm:
67-56-1
771 suppliers
$7.29/5ml-f
56-23-5
0 suppliers
$18.50/48604
124-38-9
131 suppliers
$175.00/23402
598-99-2
162 suppliers
$21.21/10gm: