meso-Tetrakis(4-chlorophenyl)porphyrin-Cu(II) synthesis
- Product Name:meso-Tetrakis(4-chlorophenyl)porphyrin-Cu(II)
- CAS Number:16828-36-7
- Molecular formula:C44H24Cl4CuN4
- Molecular Weight:814.05
Yield: 85%
Reaction Conditions:
in N,N-dimethyl-formamide for 0.00555556 h;Heating;
Steps:
Cu(II) 5,10,15,20-tetra(4-chlorophenyl)porphyrinate
A mixture of 0.02 g (0.0266 mmol) of tetra(4-chlorophenyl)porphyrin and 0.048 g (0.266 mmol) of Cu(OAc)2 in 15 mL of DMF was boiled for 20 s, then cooled, water was added, and the product was salted out. The precipitate was filtered, washed with water, dried, and chromatographed on aluminum oxides, the eluent - chloroform. Yield 0.018 g (0.0221 mmol, 85%). EAS (DMF), λ, nm (log ε): 395 (4.58), 415 (5.54), 539 (4.33), 579 (3.72). Mass-spectrum, m/z (Irel, %): 813.3 (98) [M]+ (calculated for C44H24Cl4CuN4: 814.1).
References:
Zvezdina;Chizhova;Mamardashvili, N. Zh. [Russian Journal of General Chemistry,2020,vol. 90,# 11,p. 2105 - 2110][Zh. Obshch. Khim.,2020,vol. 90,# 11,p. 1732 - 1737,6]
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