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ChemicalBook CAS DataBase List Isobutyl formate
542-55-2

Isobutyl formate synthesis

6synthesis methods
From isobutyl alcohol and carbon monoxide in the presence of sodium isobutylate at 110°C and 400 atm
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Yield:542-55-2 78 %Chromat. ,503-74-2 13 %Chromat.

Reaction Conditions:

with water;difluoro[4-(trifluoromethyl)phenyl]-λ3-bromane in dichloromethane at 0; for 1 h;Inert atmosphere;Baeyer-Villiger type oxidation;

References:

Ochiai, Masahito;Yoshimura, Akira;Miyamoto, Kazunori;Hayashi, Satoko;Nakanishi, Waro [Journal of the American Chemical Society,2010,vol. 132,# 27,p. 9236 - 9239] Location in patent:supporting information; experimental part

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