FERROCENEBORONIC ACID synthesis
- Product Name:FERROCENEBORONIC ACID
- CAS Number:12152-94-2
- Molecular formula:C10H11BFeO210*
- Molecular Weight:229.85
102-54-5
462 suppliers
$5.00/25g
688-74-4
324 suppliers
$10.40/25mL
12152-94-2
86 suppliers
$15.00/250mg
Yield:12152-94-2 60%
Reaction Conditions:
with potassium hydroxide;n-butyllithium in diethyl ether(under N2); addn. of n-BuLi and TMEDA to a stirred soln. of ferrocene in Et2O at room temp., stirred for 6 h, dropwise addn. of the suspn. to a stirred and cooled (-78°C) soln. of borate in Et2O, stirred for 12 h at room temp., hydrolysis (KOH); extg. of the organic layer with KOH, combined aq. layers are acidified with H2SO4, filtn., washing (H2O), drying (P4O10, 0.10mbar), extg. (Et2O);
References:
Knapp, Ralf;Rehahn, Matthias [Journal of Organometallic Chemistry,1993,vol. 452,# 1.2,p. 235 - 240]