DIISOPROPYL-(1H,1H,2H,2H-PERFLUOROOCTYL)SILANE synthesis
- Product Name:DIISOPROPYL-(1H,1H,2H,2H-PERFLUOROOCTYL)SILANE
- CAS Number:356056-14-9
- Molecular formula:C14H19F13Si
- Molecular Weight:462.37
2043-57-4
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2227-29-4
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356056-14-9
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$691.38/1G
Yield: 99%
Reaction Conditions:
Stage #1:1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane with tert.-butyl lithium in pentane at -78 - -15;
Stage #2:chlorodiisopropylsilane in pentane at -78 - 20;Further stages.;
References:
Zhang, Qisheng;Rivkin, Alexey;Curran, Dennis P. [Journal of the American Chemical Society,2002,vol. 124,# 20,p. 5774 - 5781]