DI-TERT-BUTYL PHOSPHITE synthesis
- Product Name:DI-TERT-BUTYL PHOSPHITE
- CAS Number:13086-84-5
- Molecular formula:C8H19O3P
- Molecular Weight:194.21
868-85-9
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75-65-0
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13086-84-5
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Yield:13086-84-5 91.5%
Reaction Conditions:
with calcium hydroxide at 130; under 760.051 Torr;Reflux;Inert atmosphere;
Steps:
6 Example 6
In a nitrogen-protected 3L round bottom three-necked flask, 110 g of dimethyl phosphite, 260 g of tert-butanol, and 3.3 g of Ca (OH)2 were added; the temperature was raised to reflux with stirring, and a fraction (methanol) of 60 to 65 ° C. was collected, and then a kettle was set. The bottom temperature is 130 ° C, and the temperature is further increased to reflux under normal pressure, and the two-stage fraction (excessive t-butanol) is distilled off. The crude di-tert-butyl phosphite is obtained at the bottom of the kettle; Further distillation under reduced pressure at a pressure of 1 kPa yielded 181.3 g of di-tert-butyl phosphite with a purity of 98% and a yield of 91.5%.
References:
CN110669069,2020,A Location in patent:Paragraph 0028
865-48-5
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13086-84-5
151 suppliers
$14.00/1g
75-65-0
767 suppliers
$10.00/10ml
13086-84-5
151 suppliers
$14.00/1g
75-65-0
767 suppliers
$10.00/10ml
13086-84-5
151 suppliers
$14.00/1g
15205-62-6
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15205-62-6
10 suppliers
inquiry
13086-84-5
151 suppliers
$14.00/1g