ChemicalBook CAS DataBase List Butyl hexanoate

Butyl hexanoate synthesis

13synthesis methods

Product Name:Butyl hexanoate
CAS Number:626-82-4
Molecular formula:C10H20O2
Molecular Weight:172.26

By esterification of hexanoic acid with n-butyl alcohol in benzene solution in the presence of p-toluene sulfonic acid; it is also formed in the fermentation of carbohydrates yielding n-butyl alcohol and acetone.

504-60-9 Synthesis

504-60-9
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$180.00/1ml

201230-82-2 Synthesis

201230-82-2
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71-36-3 Synthesis

71-36-3
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$14.00/25mL

626-82-4
202 suppliers
$8.00/25g

Yield:-

Reaction Conditions:

Stage #1:penta-1,3-diene;butan-1-ol with tris-(dibenzylideneacetone)dipalladium⁽⁰⁾;methanesulfonic acid;1,2-bis[di(t-butyl)phosphinomethyl]benzene in methanol for 0.25 h;Sonication;Schlenk technique;
Stage #2:carbon monoxide with hydrogen in methanol under 22502.3 Torr;

Steps:

3 Standard experimental procedure
General procedure: All screening experiments were performed in a 20 ml home-made multiplex reactor [48]. In an typical experiment 87.5 mg(0.10 mmol) Pd2(dba)3 and 301.8 mg (0.75 mmol) 1,2-dtbpmb,869.1 mg (12.75 mmol) piperylene, 98.0 mg (1.02 mmol) methane-sulfonic acid and 10 ml methanol were placed in a Schlenck-vessel.The mixture was placed in an ultrasonic bath for 15 min. The mix-ture was transferred to an evacuated and ame-dried reactor andsubsequently charged with 30 bar synthesis gas. The mixture wasplaced in an oil bath at reaction temperature e.g. 110 C for vehours. After cooling to room temperature the mixture was depres-surised and analysed by GC-FID.

References:

Neubert, Peter;Steffen, Matthias;Behr, Arno [Journal of Molecular Catalysis A: Chemical,2015,vol. 407,p. 122 - 127]

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142-62-1 Synthesis