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ChemicalBook CAS DataBase List ALPHA-CHLORO-3-FLUOROBENZALDOXIME
58606-42-1

ALPHA-CHLORO-3-FLUOROBENZALDOXIME synthesis

3synthesis methods
-

Yield:58606-42-1 90.2%

Reaction Conditions:

with N-chloro-succinimide in N,N-dimethyl-formamide at 35; for 3 h;

Steps:

6.B B. Preparation of chloroquinone

In a three-necked flask, m-fluorobenzaldehyde oxime (5 g, 35.9 mmol) was dissolved in N,N-dimethylformamide (100 mL), added in batches to the NCS (4.8 g, 35.9 mmol), and reacted at 35° C. for 3 h.After the reaction was completed, the reaction solution was poured into 200 ml of ethyl acetate, washed with pure water (100 mL×4), dried over anhydrous sodium sulfate, and the solvent was evaporated under reduced pressure to obtain 5.6 g of chloroquinone, with a yield of 90.2%.

References:

CN107382892,2017,A Location in patent:Paragraph 0068; 0069

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