![84592-35-8](/CAS/GIF/84592-35-8.gif)
DI-TERT-BUTYL 1-(TERT-BUTYLTHIO)-1,2-HYDRAZINEDICARBOXYLATE synthesis
- Product Name:DI-TERT-BUTYL 1-(TERT-BUTYLTHIO)-1,2-HYDRAZINEDICARBOXYLATE
- CAS Number:84592-35-8
- Molecular formula:C14H28N2O4S
- Molecular Weight:320.45
![2-Methyl-2-propanethiol](/CAS/GIF/75-66-1.gif)
75-66-1
144 suppliers
$21.00/25mL
![Di-tert-Butyl azodicarboxylate](/CAS/GIF/870-50-8.gif)
870-50-8
325 suppliers
$5.00/1g
![DI-TERT-BUTYL 1-(TERT-BUTYLTHIO)-1,2-HYDRAZINEDICARBOXYLATE](/CAS/GIF/84592-35-8.gif)
84592-35-8
21 suppliers
$941.70/5G
Yield:-
Reaction Conditions:
sodium ethanolate
Steps:
2 Preparation of 1tert.-butylthiohydrazine-1,2-dicarboxylic acid di-tert.-butyl ester
EXAMPLE 2 Preparation of 1tert.-butylthiohydrazine-1,2-dicarboxylic acid di-tert.-butyl ester A catalytic amount of sodium ethylate is added to a solution of 1.15 g. (0.005M) azodicarboxylic acid di-tert.-butyl ester and 0.57 ml. (0.005M) tert.-butylmercaptan in 20 ml. ether. The reaction proceeds exothermically. The solvent is removed in a vacuum and the oil residue is recrystallized from n-hexane. Yield 1.54 g. (96% of theoretical) Melting point 92°-96° C. C14 H28 N2 O4 S (320.45)--Theoretical: C 52.47, H 8.81, N 8.74, S 10.00. Actual: C 52.45, H 8.80, N 8.78, S 9.93.
References:
US4599407,1986,A