ChemicalBook CAS DataBase List 4-METHYLPHTHALIMIDE 99

4-METHYLPHTHALIMIDE 99 synthesis

10synthesis methods

Product Name:4-METHYLPHTHALIMIDE 99
CAS Number:40314-06-5
Molecular formula:C9H7NO2
Molecular Weight:161.16

24623-20-9 Synthesis

24623-20-9
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$16.00/1 g

40314-06-5
58 suppliers
$26.00/1g

Yield: 85%

Reaction Conditions:

with manganese(IV) oxide;ammonium hydroxide;oxygen;chlorobenzene in N,N-dimethyl-formamide at 100; under 15001.5 Torr; for 24 h;Autoclave;Green chemistry;

Steps:

6; 30 Example 30:
General procedure: 0.01g of MnO2 catalyst, 0.5mmol of 1-indanone, 0.2g of ammonia water (25wt%) and 2g of chlorobenzene were added to a stainless steel autoclave with a polytetrafluoroethylene inner liner.The temperature was raised to 110 by automatic temperature controller, 0.6MPa oxygen was added and the reaction was continued for 4h. The pressure was kept constant during the reaction.The reaction product was analyzed using GC-MS with a phthalamide yield of 85%.

References:

Dalian Institute of Chemical Physics;Wang Feng;Wang Min;Xu Jie;Ma Jiping;Yu Miao;Zhang Xiaochen;Zhang Zhe CN106278990, 2017, A Location in patent:Paragraph 0013; 0017; 0018; 0020; 0023; 0028