ChemicalBook CAS DataBase List 3-Cyclohexene-1-carboxaldehyde

3-Cyclohexene-1-carboxaldehyde synthesis

7synthesis methods

Product Name:3-Cyclohexene-1-carboxaldehyde
CAS Number:100-50-5
Molecular formula:C7H10O
Molecular Weight:110.15

106-99-0
253 suppliers
$77.00/100mL

107-02-8
4 suppliers
$38.60/4s8501

100-50-5
200 suppliers
$27.00/5mL

Yield:100-50-5 90%

Reaction Conditions:

in 1,4 dimethylcyclohexane at 150; under 30003 Torr; for 3 h;Inert atmosphere;Autoclave;Solvent;Temperature;

Steps:

2 Preparation of 3-cyclohexene-1-carbaldehyde:
To a volume of 50ml stainless steel stirred autoclave pressure was added 20g cyclohexanedimethanol as a solvent, heated and melted at 150 deg.] C maintaining the temperature, pressure and holding nitrogen thrice 4Mpa;4.8 g of acrolein and 6.2 g of 1,3-butadiene were added.While stirring, the reaction temperature was maintained at 150°C and the pressure was 4 MPa for 3 hours.Samples were analyzed by GC (gas chromatography) and the yield of cyclohexene formaldehyde was >91% based on acrolein. The unreacted acrolein and butadiene are removed by batch distillation under atmospheric pressure, and the top composition of the boiling point is 163-164°C.By GC (Gas Chromatography) detection, 3-cyclohexene-1-carbaldehyde having a purity of 99.5% was obtained for use.

References:

Wanhua Chemical Group Co., Ltd.;He Yan;Qiao Xiaofei;Zhao Yiming;Liu Junxian;Song Mingyan;Zhang Yanyu;Li Yuan CN107986943, 2018, A Location in patent:Paragraph 0059-0061; 0065-0067

FullText

201230-82-2 Synthesis